Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes
Publication type: Journal Article
Publication date: 2012-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Reactions of 1,2-bis[(hydroxymethyl)(phenyl)phosphino]ethane with primary pyridylalkylamines gave earlier unknown 1-aza-3,6-diphosphacycloheptanes containing the pyridyl group in the exocyclic substituent. The reactions were found to be stereoselective, preferentially yielding the racemate with the RR/SS-configuration of the P atoms. A mixture of diastereomers of 3,6-diphenyl-1-[2-(2-pyridyl)ethyl]-1-aza-3,6-diphosphacycloheptane reacted with dichloro(cycloocta-1,5-diene)platinum(II) to give cis-P,P-chelate complexes from the meso-isomer and bridged oligomeric complexes from the racemate.
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Total citations:
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Citations from 2024:
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(7.69%)
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GOST
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Fesenko T. I. et al. Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes // Russian Chemical Bulletin. 2012. Vol. 61. No. 9. pp. 1792-1797.
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Fesenko T. I., Strelnik I. D., Musina E. I., Karasik A. A., Sinyashin O. G. Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes // Russian Chemical Bulletin. 2012. Vol. 61. No. 9. pp. 1792-1797.
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RIS
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TY - JOUR
DO - 10.1007/s11172-012-0247-7
UR - http://link.springer.com/10.1007/s11172-012-0247-7
TI - Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes
T2 - Russian Chemical Bulletin
AU - Fesenko, T I
AU - Strelnik, I D
AU - Musina, E I
AU - Karasik, A A
AU - Sinyashin, O G
PY - 2012
DA - 2012/09/01
PB - Springer Nature
SP - 1792-1797
IS - 9
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2012_Fesenko,
author = {T I Fesenko and I D Strelnik and E I Musina and A A Karasik and O G Sinyashin},
title = {Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s11172-012-0247-7},
number = {9},
pages = {1792--1797},
doi = {10.1007/s11172-012-0247-7}
}
Cite this
MLA
Copy
Fesenko, T. I., et al. “Synthesis of 1-(pyridylalkyl)-1-aza-3,6-diphosphacycloheptanes.” Russian Chemical Bulletin, vol. 61, no. 9, Sep. 2012, pp. 1792-1797. http://link.springer.com/10.1007/s11172-012-0247-7.