Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes
S S Akimov
1
,
E Yu Matveev
1, 2
,
A. S. Kubasov
1, 2
,
G A Razgonyaeva
2
,
K Yu Zhizhin
1, 2
,
N. T. Kuznetsov
1, 2
Publication type: Journal Article
Publication date: 2013-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A reaction of the closo-decaborate anion 1,4-dioxane derivative with polyatomic alcohols (ethyleneglycol, glycerol, triethanolamine) was studied. These reactions include the ring opening of the cyclic substituent and the addition of the alcohol molecule to boron cluster through the alkoxy spacer chain. The products obtained form coordination compounds upon the reaction with gadolinium(iii) salts, playing the role of polydentate ligands. The compounds obtained were studied by IR spectroscopy, NMR spectroscopy, ESI mass spectrometry, elemental and thermographic analysis.
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Akimov S. S. et al. Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes // Russian Chemical Bulletin. 2013. Vol. 62. No. 6. pp. 1417-1421.
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Akimov S. S., Matveev E. Yu., Kubasov A. S., Razgonyaeva G. A., Zhizhin K. Yu., Kuznetsov N. T. Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes // Russian Chemical Bulletin. 2013. Vol. 62. No. 6. pp. 1417-1421.
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RIS
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TY - JOUR
DO - 10.1007/s11172-013-0204-0
UR - https://doi.org/10.1007/s11172-013-0204-0
TI - Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes
T2 - Russian Chemical Bulletin
AU - Akimov, S S
AU - Matveev, E Yu
AU - Kubasov, A. S.
AU - Razgonyaeva, G A
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2013
DA - 2013/06/01
PB - Springer Nature
SP - 1417-1421
IS - 6
VL - 62
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2013_Akimov,
author = {S S Akimov and E Yu Matveev and A. S. Kubasov and G A Razgonyaeva and K Yu Zhizhin and N. T. Kuznetsov},
title = {Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes},
journal = {Russian Chemical Bulletin},
year = {2013},
volume = {62},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-013-0204-0},
number = {6},
pages = {1417--1421},
doi = {10.1007/s11172-013-0204-0}
}
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MLA
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Akimov, S. S., et al. “Polydentate ligands based on closo-decaborate anion for the synthesis of gadolinium(iii) complexes.” Russian Chemical Bulletin, vol. 62, no. 6, Jun. 2013, pp. 1417-1421. https://doi.org/10.1007/s11172-013-0204-0.