Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile
Publication type: Journal Article
Publication date: 2013-11-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Novel organic-inorganic nanocomposites were synthesized by chemical reduction of silver ions from silver acetate in DMSO and DMF solutions in the presence of the stabilizing copolymer of 1-vinyl-1,2,4-triazole-acrylonitrile. The solvents DMSO and DMF can act as efficient reducing agents for silver ions, which makes it possible to carry out the reaction under mild conditions and simplify procedures of nanocomposite isolation. The structure and properties of the starting copolymer and related nanocomposites were characterized by UV, IR, and 1H and 13C NMR spectroscopy, as well as transmission electron microscopy and thermogravimetry. The prepared polymer nanocomposites contain 6.8–7.2% silver in the form of nanoparticles with a size of 2–20 nm uniformly dispersed in the polymer matrix. The nanocomposites are readily soluble in DMSO and DMF and do not decompose on heating to 260 °C.
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Total citations:
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Kuznetsova N. P. et al. Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile // Russian Chemical Bulletin. 2013. Vol. 62. No. 11. pp. 2509-2513.
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Kuznetsova N. P., Ermakova T. G., Pozdnyakov A. S., Emelyanov A. I., Prozorova G. F. Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile // Russian Chemical Bulletin. 2013. Vol. 62. No. 11. pp. 2509-2513.
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TY - JOUR
DO - 10.1007/s11172-013-0364-y
UR - http://link.springer.com/10.1007/s11172-013-0364-y
TI - Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile
T2 - Russian Chemical Bulletin
AU - Kuznetsova, N P
AU - Ermakova, T G
AU - Pozdnyakov, A S
AU - Emelyanov, A I
AU - Prozorova, G F
PY - 2013
DA - 2013/11/01
PB - Springer Nature
SP - 2509-2513
IS - 11
VL - 62
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2013_Kuznetsova,
author = {N P Kuznetsova and T G Ermakova and A S Pozdnyakov and A I Emelyanov and G F Prozorova},
title = {Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile},
journal = {Russian Chemical Bulletin},
year = {2013},
volume = {62},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11172-013-0364-y},
number = {11},
pages = {2509--2513},
doi = {10.1007/s11172-013-0364-y}
}
Cite this
MLA
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Kuznetsova, N. P., et al. “Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile.” Russian Chemical Bulletin, vol. 62, no. 11, Nov. 2013, pp. 2509-2513. http://link.springer.com/10.1007/s11172-013-0364-y.