Russian Chemical Bulletin

, том 62 , издание 11 , страницы 2509-2513

Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile

N P Kuznetsova ¹

T G Ermakova ¹

A S Pozdnyakov ¹

A I Emelyanov ¹

G F Prozorova ¹

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A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russian Federation |

Тип публикации: Journal Article

Дата публикации: 2013-11-01

Springer Nature

Russian Chemical Bulletin

scimago Q3

БС2

SJR: 0.305

CiteScore: 2.8

Impact factor: —

ISSN: 10665285, 15739171

DOI: 10.1007/s11172-013-0364-y

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General Chemistry

Краткое описание

Novel organic-inorganic nanocomposites were synthesized by chemical reduction of silver ions from silver acetate in DMSO and DMF solutions in the presence of the stabilizing copolymer of 1-vinyl-1,2,4-triazole-acrylonitrile. The solvents DMSO and DMF can act as efficient reducing agents for silver ions, which makes it possible to carry out the reaction under mild conditions and simplify procedures of nanocomposite isolation. The structure and properties of the starting copolymer and related nanocomposites were characterized by UV, IR, and 1H and 13C NMR spectroscopy, as well as transmission electron microscopy and thermogravimetry. The prepared polymer nanocomposites contain 6.8–7.2% silver in the form of nanoparticles with a size of 2–20 nm uniformly dispersed in the polymer matrix. The nanocomposites are readily soluble in DMSO and DMF and do not decompose on heating to 260 °C.

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Биологическая активность

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Центр Фотохимии

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Национальный университет Чунгнам

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Kuznetsova N. P. et al. Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile // Russian Chemical Bulletin. 2013. Vol. 62. No. 11. pp. 2509-2513.

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Kuznetsova N. P., Ermakova T. G., Pozdnyakov A. S., Emelyanov A. I., Prozorova G. F. Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile // Russian Chemical Bulletin. 2013. Vol. 62. No. 11. pp. 2509-2513.

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TY - JOUR

DO - 10.1007/s11172-013-0364-y

UR - http://link.springer.com/10.1007/s11172-013-0364-y

TI - Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile

T2 - Russian Chemical Bulletin

AU - Kuznetsova, N P

AU - Ermakova, T G

AU - Pozdnyakov, A S

AU - Emelyanov, A I

AU - Prozorova, G F

PY - 2013

DA - 2013/11/01

PB - Springer Nature

SP - 2509-2513

IS - 11

VL - 62

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2013_Kuznetsova,

author = {N P Kuznetsova and T G Ermakova and A S Pozdnyakov and A I Emelyanov and G F Prozorova},

title = {Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile},

journal = {Russian Chemical Bulletin},

year = {2013},

volume = {62},

publisher = {Springer Nature},

month = {nov},

url = {http://link.springer.com/10.1007/s11172-013-0364-y},

number = {11},

pages = {2509--2513},

doi = {10.1007/s11172-013-0364-y}

}

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Kuznetsova, N. P., et al. “Synthesis and characterization of silver polymer nanocomposites of 1-vinyl-1,2,4-triazole with acrylonitrile.” Russian Chemical Bulletin, vol. 62, no. 11, Nov. 2013, pp. 2509-2513. http://link.springer.com/10.1007/s11172-013-0364-y.

Издатель

Springer Nature

Журнал

Russian Chemical Bulletin

scimago Q3

БС2

SJR

0.305

CiteScore

2.8

Impact factor

—

ISSN

10665285 (Print)

15739171 (Electronic)

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