Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts
A. V. Chistyakov
1
,
M A Gubanov
1
,
V Yu Murzin
1, 2
,
P A Zharova
1
,
M V Tsodikov
1
,
V.V. Kriventsov
3
,
A E Gekhman
4
,
I. I. Moiseev
4
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The features of ethanol conversion into hydrocarbons C4-C12 in the presence of the novel catalyst Pd-Zn/γ-alumina and pilot zeolite system Pd-Zn/MFI/γ-alumina were studied (MFI is high-siliceous zeolite with ZSM-5 type structure). The structure of active sites changes noticeably in the course of preliminary activation and catalytic reaction. High selectivity and stability of the zeolite-containing Pd-Zn catalyst in alcohol conversion into hydrocarbon components of fuels is related to the stable composition of the alloy that forms clusters PdZn. At the same time, the alumina-based catalyst loses stability due to zinc diffusion from the alloy into γ-Al2O3 to form the spinel structure.
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Chistyakov A. V. et al. Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts // Russian Chemical Bulletin. 2014. Vol. 63. No. 1. pp. 88-93.
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Chistyakov A. V., Gubanov M. A., Murzin V. Yu., Zharova P. A., Tsodikov M. V., Kriventsov V., Gekhman A. E., Moiseev I. I. Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts // Russian Chemical Bulletin. 2014. Vol. 63. No. 1. pp. 88-93.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-014-0399-8
UR - https://doi.org/10.1007/s11172-014-0399-8
TI - Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts
T2 - Russian Chemical Bulletin
AU - Chistyakov, A. V.
AU - Gubanov, M A
AU - Murzin, V Yu
AU - Zharova, P A
AU - Tsodikov, M V
AU - Kriventsov, V.V.
AU - Gekhman, A E
AU - Moiseev, I. I.
PY - 2014
DA - 2014/01/01
PB - Springer Nature
SP - 88-93
IS - 1
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Chistyakov,
author = {A. V. Chistyakov and M A Gubanov and V Yu Murzin and P A Zharova and M V Tsodikov and V.V. Kriventsov and A E Gekhman and I. I. Moiseev},
title = {Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-014-0399-8},
number = {1},
pages = {88--93},
doi = {10.1007/s11172-014-0399-8}
}
Cite this
MLA
Copy
Chistyakov, A. V., et al. “Conversion of ethanol into hydrocarbon components of fuels in the presence of Pd-Zn-containing catalysts.” Russian Chemical Bulletin, vol. 63, no. 1, Jan. 2014, pp. 88-93. https://doi.org/10.1007/s11172-014-0399-8.
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