Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations
Тип публикации: Journal Article
Дата публикации: 2014-04-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
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ISSN: 10665285, 15739171
General Chemistry
Краткое описание
The reactions of triphenylantimony(V) catecholates (Cat)SbPh3 with different tetraalkyl-ammonium salts (bromides, iodides, hydroxide anions) in acetonitrile were investigated, and their complexes 8–13 of the general formula [R4N]+[(Cat)SbPh3X]− were synthesized. The molecular structure of complex 8 was determined by X-ray diffraction. The electrochemical oxidation of complexes 8–13 proceeds more easily than the oxidation of the starting catecholates (Cat)SbPh3. The coordination of the bromide anion results in the stabilization of the oxidized forms of the complexes [(SQ)SbPh3X]0 and [(Q)SbPh3X]+ (SQ and Q are the o-benzosemiquinone and o-benzoquinone forms of the redox-active ligand, respectively).
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Poddelskii A. I. et al. Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 923-929.
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Poddelskii A. I., Ilyakina E. V., Smolyaninov I. V., Fukin G. K., Berberova N. T., Cherkasov V. K., Abakumov G. A. Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 923-929.
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TY - JOUR
DO - 10.1007/s11172-014-0529-3
UR - https://doi.org/10.1007/s11172-014-0529-3
TI - Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations
T2 - Russian Chemical Bulletin
AU - Poddelskii, A I
AU - Ilyakina, E V
AU - Smolyaninov, I V
AU - Fukin, G. K.
AU - Berberova, N T
AU - Cherkasov, V. K.
AU - Abakumov, G. A.
PY - 2014
DA - 2014/04/01
PB - Springer Nature
SP - 923-929
IS - 4
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2014_Poddelskii,
author = {A I Poddelskii and E V Ilyakina and I V Smolyaninov and G. K. Fukin and N T Berberova and V. K. Cherkasov and G. A. Abakumov},
title = {Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-014-0529-3},
number = {4},
pages = {923--929},
doi = {10.1007/s11172-014-0529-3}
}
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MLA
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Poddelskii, A. I., et al. “Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations.” Russian Chemical Bulletin, vol. 63, no. 4, Apr. 2014, pp. 923-929. https://doi.org/10.1007/s11172-014-0529-3.
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