Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations
A I Poddelskii
1, 2
,
E V Ilyakina
1, 2
,
I V Smolyaninov
3
,
G. K. Fukin
1
,
N T Berberova
1, 3
,
V. K. Cherkasov
2
,
G. A. Abakumov
1
Publication type: Journal Article
Publication date: 2014-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reactions of triphenylantimony(V) catecholates (Cat)SbPh3 with different tetraalkyl-ammonium salts (bromides, iodides, hydroxide anions) in acetonitrile were investigated, and their complexes 8–13 of the general formula [R4N]+[(Cat)SbPh3X]− were synthesized. The molecular structure of complex 8 was determined by X-ray diffraction. The electrochemical oxidation of complexes 8–13 proceeds more easily than the oxidation of the starting catecholates (Cat)SbPh3. The coordination of the bromide anion results in the stabilization of the oxidized forms of the complexes [(SQ)SbPh3X]0 and [(Q)SbPh3X]+ (SQ and Q are the o-benzosemiquinone and o-benzoquinone forms of the redox-active ligand, respectively).
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16
Total citations:
16
Citations from 2024:
2
(12%)
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GOST
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Poddelskii A. I. et al. Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 923-929.
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Poddelskii A. I., Ilyakina E. V., Smolyaninov I. V., Fukin G. K., Berberova N. T., Cherkasov V. K., Abakumov G. A. Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 923-929.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-014-0529-3
UR - https://doi.org/10.1007/s11172-014-0529-3
TI - Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations
T2 - Russian Chemical Bulletin
AU - Poddelskii, A I
AU - Ilyakina, E V
AU - Smolyaninov, I V
AU - Fukin, G. K.
AU - Berberova, N T
AU - Cherkasov, V. K.
AU - Abakumov, G. A.
PY - 2014
DA - 2014/04/01
PB - Springer Nature
SP - 923-929
IS - 4
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2014_Poddelskii,
author = {A I Poddelskii and E V Ilyakina and I V Smolyaninov and G. K. Fukin and N T Berberova and V. K. Cherkasov and G. A. Abakumov},
title = {Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-014-0529-3},
number = {4},
pages = {923--929},
doi = {10.1007/s11172-014-0529-3}
}
Cite this
MLA
Copy
Poddelskii, A. I., et al. “Complexes of triphenylantimony(v) catecholates with ammonium salts. Spectroscopic and electrochemical investigations.” Russian Chemical Bulletin, vol. 63, no. 4, Apr. 2014, pp. 923-929. https://doi.org/10.1007/s11172-014-0529-3.
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