том 64 издание 1 страницы 38-43

Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers

Тип публикацииJournal Article
Дата публикации2015-01-01
scimago Q3
БС2
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Краткое описание
Reduction of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian, 1) with metallic europium in 1,2-dimethoxyethane (dme) under anaerobic conditions gave a europium(II) complex with the acenaphthene-1,2-diimine dianion, (dpp-bian)Eu(dme)2 (4), in high yield. Oxidation of complex 4 with triphenyltin chloride or 1,2-dibromostilbene afforded the corresponding halogen derivatives [(dpp-bian)Eu(µ-Cl)(dme)]2 (5) and [(dpp-bian)Eu(µ-Br)(dme)]2 (6). The molecular structures of complexes 4–6 were determined by X-ray diffraction. The magnetic moments of complexes 5 and 6 remain constant over a temperature range from 25 to 295 K; they are indicative of the presence of the europium(II) ion and the dpp-bian radical anion in both the complexes.
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ГОСТ |
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Fedushkin I. L. et al. Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers // Russian Chemical Bulletin. 2015. Vol. 64. No. 1. pp. 38-43.
ГОСТ со всеми авторами (до 50) Скопировать
Fedushkin I. L., Skatova A. A., Yambulatov D. S., Cherkasov A. V., Demeshko S. V. Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers // Russian Chemical Bulletin. 2015. Vol. 64. No. 1. pp. 38-43.
RIS |
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TY - JOUR
DO - 10.1007/s11172-015-0817-6
UR - https://doi.org/10.1007/s11172-015-0817-6
TI - Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers
T2 - Russian Chemical Bulletin
AU - Fedushkin, I L
AU - Skatova, A A
AU - Yambulatov, D S
AU - Cherkasov, A. V.
AU - Demeshko, S V
PY - 2015
DA - 2015/01/01
PB - Springer Nature
SP - 38-43
IS - 1
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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@article{2015_Fedushkin,
author = {I L Fedushkin and A A Skatova and D S Yambulatov and A. V. Cherkasov and S V Demeshko},
title = {Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-015-0817-6},
number = {1},
pages = {38--43},
doi = {10.1007/s11172-015-0817-6}
}
MLA
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Fedushkin, I. L., et al. “Europium complexes with 1,2-bis(arylimino)acenaphthenes: a search for redox isomers.” Russian Chemical Bulletin, vol. 64, no. 1, Jan. 2015, pp. 38-43. https://doi.org/10.1007/s11172-015-0817-6.