Hepta(methoxycarbonyl)cycloheptatriene halo derivatives
Publication type: Journal Article
Publication date: 2015-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A reaction of potassium hepta(methoxycarbonyl)cycloheptatrienide with chlorine and bromine gave high yields of the corresponding chloroand bromohepta(methoxycarbonyl)cycloheptatrienes; the fluoro derivative was obtained by the exchange reaction of the corresponding bromide with silver fluoride. In contrast to the mentioned halides, the iodo derivative has proved unstable. Thermolysis of bromohepta(methoxycarbonyl)cycloheptatriene was studied, as well as its conversion to the azido and methoxy derivatives upon treatment with NaN3 or methanol.
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Platonov D. N. et al. Hepta(methoxycarbonyl)cycloheptatriene halo derivatives // Russian Chemical Bulletin. 2015. Vol. 64. No. 1. pp. 241-245.
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Platonov D. N., Okonnishnikova G. P., Levina A. A., Tomilov Yu. V. Hepta(methoxycarbonyl)cycloheptatriene halo derivatives // Russian Chemical Bulletin. 2015. Vol. 64. No. 1. pp. 241-245.
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TY - JOUR
DO - 10.1007/s11172-015-0851-4
UR - https://doi.org/10.1007/s11172-015-0851-4
TI - Hepta(methoxycarbonyl)cycloheptatriene halo derivatives
T2 - Russian Chemical Bulletin
AU - Platonov, D N
AU - Okonnishnikova, G P
AU - Levina, A A
AU - Tomilov, Yu V
PY - 2015
DA - 2015/01/01
PB - Springer Nature
SP - 241-245
IS - 1
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2015_Platonov,
author = {D N Platonov and G P Okonnishnikova and A A Levina and Yu V Tomilov},
title = {Hepta(methoxycarbonyl)cycloheptatriene halo derivatives},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-015-0851-4},
number = {1},
pages = {241--245},
doi = {10.1007/s11172-015-0851-4}
}
Cite this
MLA
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Platonov, D. N., et al. “Hepta(methoxycarbonyl)cycloheptatriene halo derivatives.” Russian Chemical Bulletin, vol. 64, no. 1, Jan. 2015, pp. 241-245. https://doi.org/10.1007/s11172-015-0851-4.