Springer Nature
Russian Chemical Bulletin
,  volume 64 ,  issue 9 ,  pages 2062-2068

Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst

Publication type: Journal Article
Publication date: 2015-09-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
We studied deoxygenation of individual fatty esters and fatty acid triglycerides from vegetable oils and lipid extracts from microalgae in the presence of catalysts prepared by deposition of Pt–Sn-containing compounds onto the γ-aluminum oxide surface. Using individual esters as an example, selective reduction of oxygen into water was demonstrated for the first time to proceed on a catalytic system at the 5 : 1 molar ratio of Sn and Pt active components to afford hydrocarbon components of substrates in virtually quantitative yield. Transformation of vegetable oil in the presence of this catalyst affords the C3–C18 hydrocarbon fraction in yield up to 99% at the content of C3 and C18 hydrocarbons up to 90%. The fraction of C1 and C2 hydrocarbons and carbon oxides is not higher than 0.5%. The possibility of carbon weight loss minimization during transformation of lipids was shown for the first time.
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GOST Copy
Tsodikov M. V. et al. Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst // Russian Chemical Bulletin. 2015. Vol. 64. No. 9. pp. 2062-2068.
GOST all authors (up to 50) Copy
Tsodikov M. V., Chistyakov A. V., Gubanov M. A., Zharova P. A., Shapovalov S. S., Pasynskii A. A., Kriventsov V., Moiseev I. I. Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst // Russian Chemical Bulletin. 2015. Vol. 64. No. 9. pp. 2062-2068.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s11172-015-1118-9
UR - https://doi.org/10.1007/s11172-015-1118-9
TI - Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst
T2 - Russian Chemical Bulletin
AU - Tsodikov, M V
AU - Chistyakov, A. V.
AU - Gubanov, M A
AU - Zharova, P A
AU - Shapovalov, S S
AU - Pasynskii, A A
AU - Kriventsov, V.V.
AU - Moiseev, I. I.
PY - 2015
DA - 2015/09/01
PB - Springer Nature
SP - 2062-2068
IS - 9
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Tsodikov,
author = {M V Tsodikov and A. V. Chistyakov and M A Gubanov and P A Zharova and S S Shapovalov and A A Pasynskii and V.V. Kriventsov and I. I. Moiseev},
title = {Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s11172-015-1118-9},
number = {9},
pages = {2062--2068},
doi = {10.1007/s11172-015-1118-9}
}
MLA
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MLA Copy
Tsodikov, M. V., et al. “Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst.” Russian Chemical Bulletin, vol. 64, no. 9, Sep. 2015, pp. 2062-2068. https://doi.org/10.1007/s11172-015-1118-9.