[2+2] Cycloaddition of the Schrock titanium silylidene and acetylene
Publication type: Journal Article
Publication date: 2016-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
[2+2] Cycloadduct of the titanium silylidene Cp2Ti(thf)=Si[Si3(SiMeBut 2)4] and acetylene was readily prepared, isolated, and characterized by NMR spectroscopy and computational studies of the Me3Si-substituted model. Geometric features of the model, based on its optimized geometry, suggest that the best structural description for such [2+2] cycloadduct is a metallacycle rather than a π complex.
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Lee V. Ya. et al. [2+2] Cycloaddition of the Schrock titanium silylidene and acetylene // Russian Chemical Bulletin. 2016. Vol. 65. No. 4. pp. 1139-1141.
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Lee V. Ya., Gapurenko O. A., Minkin V. I., Horiguchi S., Sekiguchi A. [2+2] Cycloaddition of the Schrock titanium silylidene and acetylene // Russian Chemical Bulletin. 2016. Vol. 65. No. 4. pp. 1139-1141.
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TY - JOUR
DO - 10.1007/s11172-016-1425-9
UR - https://doi.org/10.1007/s11172-016-1425-9
TI - [2+2] Cycloaddition of the Schrock titanium silylidene and acetylene
T2 - Russian Chemical Bulletin
AU - Lee, V Ya
AU - Gapurenko, O A
AU - Minkin, V I
AU - Horiguchi, S
AU - Sekiguchi, A.
PY - 2016
DA - 2016/04/01
PB - Springer Nature
SP - 1139-1141
IS - 4
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2016_Lee,
author = {V Ya Lee and O A Gapurenko and V I Minkin and S Horiguchi and A. Sekiguchi},
title = {[2+2] Cycloaddition of the Schrock titanium silylidene and acetylene},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-016-1425-9},
number = {4},
pages = {1139--1141},
doi = {10.1007/s11172-016-1425-9}
}
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MLA
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Lee, V. Ya., et al. “[2+2] Cycloaddition of the Schrock titanium silylidene and acetylene.” Russian Chemical Bulletin, vol. 65, no. 4, Apr. 2016, pp. 1139-1141. https://doi.org/10.1007/s11172-016-1425-9.
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