Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole
A V Nemtarev
1, 2
,
V F Mironov
1, 2
,
A S Aniskin
1
,
D.S. Baranov
3
,
D.B. Krivolapov
1
,
R Z Musin
1
,
S F Vasilevskii
3
Publication type: Journal Article
Publication date: 2016-05-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Reactions of 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole with 2-, 3-, 4-methoxyphenyl-, 3,4-dimethoxyphenyl- and 2,3,4-trimethoxyphenylacetylenes furnished 4-phenylbenzo-1,2-oxaphosphinine derivatives. The presence of one, two, or three donor methoxy groups in the aromatic ring of phenylacetylene does not change the general direction of the reaction which is characteristic of arylacetylenes and lead to 4-arylareno-1,2-oxaphosphinine derivatives. The presence of substituents in the exocyclic aryl group at ortho-position to the oxaphosphinine ring led to the appearance of atropoisomers.
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Nemtarev A. V. et al. Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole // Russian Chemical Bulletin. 2016. Vol. 65. No. 5. pp. 1299-1307.
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Nemtarev A. V., Mironov V. F., Aniskin A. S., Baranov D., Krivolapov D., Musin R. Z., Vasilevskii S. F. Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole // Russian Chemical Bulletin. 2016. Vol. 65. No. 5. pp. 1299-1307.
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TY - JOUR
DO - 10.1007/s11172-016-1452-6
UR - https://doi.org/10.1007/s11172-016-1452-6
TI - Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole
T2 - Russian Chemical Bulletin
AU - Nemtarev, A V
AU - Mironov, V F
AU - Aniskin, A S
AU - Baranov, D.S.
AU - Krivolapov, D.B.
AU - Musin, R Z
AU - Vasilevskii, S F
PY - 2016
DA - 2016/05/01
PB - Springer Nature
SP - 1299-1307
IS - 5
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2016_Nemtarev,
author = {A V Nemtarev and V F Mironov and A S Aniskin and D.S. Baranov and D.B. Krivolapov and R Z Musin and S F Vasilevskii},
title = {Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s11172-016-1452-6},
number = {5},
pages = {1299--1307},
doi = {10.1007/s11172-016-1452-6}
}
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MLA
Copy
Nemtarev, A. V., et al. “Reactions of arylenedioxytrihalophosphoranes with acetylenes 14. Methoxyphenylacetylenes in the reaction with 2,2,2-trichlorobenzo-1,3,2-dioxaphosphole.” Russian Chemical Bulletin, vol. 65, no. 5, May. 2016, pp. 1299-1307. https://doi.org/10.1007/s11172-016-1452-6.