New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene
A F Asachenko
1
,
A. A. Bush
1
,
A. YU. SMIRNOV
1
,
O S Morozov
1
,
P B Dzhevakov
1
,
S Y Kim
2
,
M.S. Cho
2
,
K S Lee
2
,
Y. H. Lee
2
,
K. J. Cho
2
,
S. M. Lee
2
,
M S Nechaev
1, 3
2
LGChem Research Park, Basic Material R&D, Daejeon, South Korea
|
Publication type: Journal Article
Publication date: 2016-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A series of symmetric and nonsymmetric tetrahydroindenyl zirconium complexes was obtained by the reaction of ZrCl4 or (CpTMS)ZrCl3 with lithium salts of the corresponding tetrahydroindenes. Activated with methylalumoxane, these complexes exhibit high activity in polymerization of ethylene (up to 6.8∙106 g PE (mol Zr h)–1), as well as in copolymerization of ethylene and hex-1-ene (up to 8.6∙106 g PE (mol Zr h)–1).
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Asachenko A. F. et al. New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene // Russian Chemical Bulletin. 2016. Vol. 65. No. 6. pp. 1580-1585.
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Asachenko A. F., Bush A. A., SMIRNOV A. Y., Morozov O. S., Dzhevakov P. B., Kim S. Y., Cho M., Lee K. S., Lee Y. H., Cho K. J., Lee S. M., Nechaev M. S. New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene // Russian Chemical Bulletin. 2016. Vol. 65. No. 6. pp. 1580-1585.
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TY - JOUR
DO - 10.1007/s11172-016-1485-x
UR - https://doi.org/10.1007/s11172-016-1485-x
TI - New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene
T2 - Russian Chemical Bulletin
AU - Asachenko, A F
AU - Bush, A. A.
AU - SMIRNOV, A. YU.
AU - Morozov, O S
AU - Dzhevakov, P B
AU - Kim, S Y
AU - Cho, M.S.
AU - Lee, K S
AU - Lee, Y. H.
AU - Cho, K. J.
AU - Lee, S. M.
AU - Nechaev, M S
PY - 2016
DA - 2016/06/01
PB - Springer Nature
SP - 1580-1585
IS - 6
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2016_Asachenko,
author = {A F Asachenko and A. A. Bush and A. YU. SMIRNOV and O S Morozov and P B Dzhevakov and S Y Kim and M.S. Cho and K S Lee and Y. H. Lee and K. J. Cho and S. M. Lee and M S Nechaev},
title = {New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-016-1485-x},
number = {6},
pages = {1580--1585},
doi = {10.1007/s11172-016-1485-x}
}
Cite this
MLA
Copy
Asachenko, A. F., et al. “New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene.” Russian Chemical Bulletin, vol. 65, no. 6, Jun. 2016, pp. 1580-1585. https://doi.org/10.1007/s11172-016-1485-x.
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