Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes
A.I. Vedernikov
1
,
V N Nuriev
2
,
O.V. Fedorov
3
,
A A Moiseeva
2
,
N A Kurchavov
1
,
L. G. Kuz'mina
4
,
A Ya Freidzon
1, 5
,
E S Podyacheva
2
,
A V Medvedko
2
,
S. Z. Vatsadze
2
,
S P Gromov
1, 2
Publication type: Journal Article
Publication date: 2016-11-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
An improved method for the synthesis of two symmetric biscrown-containing and one model tetramethoxy-substituted 1,4-distyrylbenzenes was suggested. The structures of compounds were established by 1H and 13C NMR spectroscopy and X-ray diffraction analysis. Spectrophotometric and fluorescent titration were used to determine spectral properties, stoichiometry, and stability of complexes of biscrown-containing 1,4-distyrylbenzenes with alkali and alkaline-earth metal cations. The stability of the complexes was found to depend on the metal cation size and charge, as well as on the size of the crown ether fragment. The electrochemical oxidation and reduction potentials of the biscrown-containing 1,4-distyrylbenzenes and the model compound in solution were determined and their basic differences from the corresponding characteristics of biscrown-containing stilbenes were identified.
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11
Total citations:
11
Citations from 2024:
1
(9%)
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GOST
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Vedernikov A. et al. Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes // Russian Chemical Bulletin. 2016. Vol. 65. No. 11. pp. 2686-2703.
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Vedernikov A., Nuriev V. N., Fedorov O., Moiseeva A. A., Kurchavov N. A., Kuz'mina L. G., Freidzon A. Ya., Podyacheva E. S., Medvedko A. V., Vatsadze S. Z., Gromov S. P. Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes // Russian Chemical Bulletin. 2016. Vol. 65. No. 11. pp. 2686-2703.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-016-1637-z
UR - http://link.springer.com/10.1007/s11172-016-1637-z
TI - Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes
T2 - Russian Chemical Bulletin
AU - Vedernikov, A.I.
AU - Nuriev, V N
AU - Fedorov, O.V.
AU - Moiseeva, A A
AU - Kurchavov, N A
AU - Kuz'mina, L. G.
AU - Freidzon, A Ya
AU - Podyacheva, E S
AU - Medvedko, A V
AU - Vatsadze, S. Z.
AU - Gromov, S P
PY - 2016
DA - 2016/11/01
PB - Springer Nature
SP - 2686-2703
IS - 11
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2016_Vedernikov,
author = {A.I. Vedernikov and V N Nuriev and O.V. Fedorov and A A Moiseeva and N A Kurchavov and L. G. Kuz'mina and A Ya Freidzon and E S Podyacheva and A V Medvedko and S. Z. Vatsadze and S P Gromov},
title = {Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11172-016-1637-z},
number = {11},
pages = {2686--2703},
doi = {10.1007/s11172-016-1637-z}
}
Cite this
MLA
Copy
Vedernikov, A.I., et al. “Synthesis, structure and complexation of biscrown-containing 1,4-distyrylbenzenes.” Russian Chemical Bulletin, vol. 65, no. 11, Nov. 2016, pp. 2686-2703. http://link.springer.com/10.1007/s11172-016-1637-z.