Springer Nature
Russian Chemical Bulletin
,  volume 66 ,  issue 6 ,  pages 1088-1093

Kinetic parameters of cationic polymerization of 1,3-dienes

Publication type: Journal Article
Publication date: 2017-06-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A new technique for the determination of the concentration of active centers of polymerization and propagation rate constants for processes of cationic polymerization of conjugated dienes was proposed. The method consists of the quantitative calculation from the 13C NMR spectra of the concentration of the initial units of the polymer chain polydienes synthesized at different monomer conversions and the subsequent extrapolation of the obtained values to the zero monomer conversion. Using the proposed procedure, the chain propagation rate constants were determined for the cationic polymerization of isoprene and 1,3-pentadiene in the presence of a titanium tetrachloride–tert-butyl chloride catalytic system.
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GOST Copy
Rozentsvet V. A. et al. Kinetic parameters of cationic polymerization of 1,3-dienes // Russian Chemical Bulletin. 2017. Vol. 66. No. 6. pp. 1088-1093.
GOST all authors (up to 50) Copy
Rozentsvet V. A., Kozlov V. G., Stotskaya O. A., Sablina N. A., Ivanova V. P., Tolstoy P. M. Kinetic parameters of cationic polymerization of 1,3-dienes // Russian Chemical Bulletin. 2017. Vol. 66. No. 6. pp. 1088-1093.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s11172-017-1858-9
UR - https://doi.org/10.1007/s11172-017-1858-9
TI - Kinetic parameters of cationic polymerization of 1,3-dienes
T2 - Russian Chemical Bulletin
AU - Rozentsvet, V A
AU - Kozlov, V. G.
AU - Stotskaya, O A
AU - Sablina, N A
AU - Ivanova, V. P.
AU - Tolstoy, P M
PY - 2017
DA - 2017/06/01
PB - Springer Nature
SP - 1088-1093
IS - 6
VL - 66
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Rozentsvet,
author = {V A Rozentsvet and V. G. Kozlov and O A Stotskaya and N A Sablina and V. P. Ivanova and P M Tolstoy},
title = {Kinetic parameters of cationic polymerization of 1,3-dienes},
journal = {Russian Chemical Bulletin},
year = {2017},
volume = {66},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-017-1858-9},
number = {6},
pages = {1088--1093},
doi = {10.1007/s11172-017-1858-9}
}
MLA
Cite this
MLA Copy
Rozentsvet, V. A., et al. “Kinetic parameters of cationic polymerization of 1,3-dienes.” Russian Chemical Bulletin, vol. 66, no. 6, Jun. 2017, pp. 1088-1093. https://doi.org/10.1007/s11172-017-1858-9.
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