Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction
Тип публикации: Journal Article
Дата публикации: 2018-01-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
The palladium complexes of the Pd-PEPPSI type with N-heterocyclic carbenes of the 1,2,4-triazole series were synthesized in 76—99% yields by the reactions of PdCl2 with 1,4-di- alkyl-1,2,4-triazolium salts in pyridine in the presence of KBr or KI as sources of halide ions and tetrabutylammonium salts as phase-transfer catalysts. The obtained complexes can be used as efficient catalysts for the Suzuki—Miyaura cross-coupling and are not inferior to the commercially available Pd-PEPPSI catalysts in activity.
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Chernenko A. Yu. et al. Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction // Russian Chemical Bulletin. 2018. Vol. 67. No. 1. pp. 79-84.
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Chernenko A. Yu., Astakhov A. V., Pasyukov D. V., Dorovatovskii P. V., Zubavichus Y. V., Khrustalev V. N., Chernyshev V. M. Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction // Russian Chemical Bulletin. 2018. Vol. 67. No. 1. pp. 79-84.
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TY - JOUR
DO - 10.1007/s11172-018-2040-8
UR - https://doi.org/10.1007/s11172-018-2040-8
TI - Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction
T2 - Russian Chemical Bulletin
AU - Chernenko, A Yu
AU - Astakhov, A V
AU - Pasyukov, D V
AU - Dorovatovskii, P. V.
AU - Zubavichus, Ya. V.
AU - Khrustalev, V. N.
AU - Chernyshev, V M
PY - 2018
DA - 2018/01/01
PB - Springer Nature
SP - 79-84
IS - 1
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2018_Chernenko,
author = {A Yu Chernenko and A V Astakhov and D V Pasyukov and P. V. Dorovatovskii and Ya. V. Zubavichus and V. N. Khrustalev and V M Chernyshev},
title = {Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-018-2040-8},
number = {1},
pages = {79--84},
doi = {10.1007/s11172-018-2040-8}
}
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Chernenko, A. Yu., et al. “Pd-PEPPSI complexes based on 1,2,4-triazol-3-ylidene ligands as efficient catalysts in the Suzuki—Miyaura reaction.” Russian Chemical Bulletin, vol. 67, no. 1, Jan. 2018, pp. 79-84. https://doi.org/10.1007/s11172-018-2040-8.
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