Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions
Publication type: Journal Article
Publication date: 2018-07-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Cadmium(II) chelates with 4-iodo-, 5,5´-, and 4,4´-dibromo-2,2´-dipyrromethenes (HL1, HL2, and HL3, respectively) with the composition of [CdL2] were synthesized. The influence of structural features of their molecules and properties of the medium on the characteristics of absorption and fluorescence spectra, and also on the thermodynamic stability constants in solutions was evaluated. The results of quantum chemical calculations revealed that the additional coordination interactions between the bromine atoms at the α-positions of dipyrromethene ligands and the complexing atom are possible in the molecular structure of α,α´- dibromosubstituted dipyrromethenate [Cd(L2)2] in contrast with β-halogenated analogues [Cd(L1)2] and [Cd(L3)2].
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Nuraneeva E. N. et al. Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions // Russian Chemical Bulletin. 2018. Vol. 67. No. 7. pp. 1231-1240.
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Nuraneeva E. N., Guseva G. B., Antina E. V., Berezin M. B., Ksenofontov A. A. Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions // Russian Chemical Bulletin. 2018. Vol. 67. No. 7. pp. 1231-1240.
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TY - JOUR
DO - 10.1007/s11172-018-2206-4
UR - https://doi.org/10.1007/s11172-018-2206-4
TI - Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions
T2 - Russian Chemical Bulletin
AU - Nuraneeva, E N
AU - Guseva, G B
AU - Antina, E V
AU - Berezin, M B
AU - Ksenofontov, A A
PY - 2018
DA - 2018/07/01
PB - Springer Nature
SP - 1231-1240
IS - 7
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2018_Nuraneeva,
author = {E N Nuraneeva and G B Guseva and E V Antina and M B Berezin and A A Ksenofontov},
title = {Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/s11172-018-2206-4},
number = {7},
pages = {1231--1240},
doi = {10.1007/s11172-018-2206-4}
}
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MLA
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Nuraneeva, E. N., et al. “Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions.” Russian Chemical Bulletin, vol. 67, no. 7, Jul. 2018, pp. 1231-1240. https://doi.org/10.1007/s11172-018-2206-4.