Russian Chemical Bulletin, volume 67, issue 7, pages 1231-1240

Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions

Publication typeJournal Article
Publication date2018-07-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.7
ISSN10665285, 15739171
General Chemistry
Abstract
Cadmium(II) chelates with 4-iodo-, 5,5´-, and 4,4´-dibromo-2,2´-dipyrromethenes (HL1, HL2, and HL3, respectively) with the composition of [CdL2] were synthesized. The influence of structural features of their molecules and properties of the medium on the characteristics of absorption and fluorescence spectra, and also on the thermodynamic stability constants in solutions was evaluated. The results of quantum chemical calculations revealed that the additional coordination interactions between the bromine atoms at the α-positions of dipyrromethene ligands and the complexing atom are possible in the molecular structure of α,α´- dibromosubstituted dipyrromethenate [Cd(L2)2] in contrast with β-halogenated analogues [Cd(L1)2] and [Cd(L3)2].

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Nuraneeva E. N. et al. Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions // Russian Chemical Bulletin. 2018. Vol. 67. No. 7. pp. 1231-1240.
GOST all authors (up to 50) Copy
Nuraneeva E. N., Guseva G. B., Antina E. V., Berezin M. B., Ksenofontov A. A. Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions // Russian Chemical Bulletin. 2018. Vol. 67. No. 7. pp. 1231-1240.
RIS |
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TY - JOUR
DO - 10.1007/s11172-018-2206-4
UR - https://doi.org/10.1007%2Fs11172-018-2206-4
TI - Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions
T2 - Russian Chemical Bulletin
AU - Berezin, M B
AU - Ksenofontov, A A
AU - Nuraneeva, E N
AU - Guseva, G B
AU - Antina, E V
PY - 2018
DA - 2018/07/01 00:00:00
PB - Springer Nature
SP - 1231-1240
IS - 7
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex Copy
@article{2018_Nuraneeva
author = {M B Berezin and A A Ksenofontov and E N Nuraneeva and G B Guseva and E V Antina},
title = {Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007%2Fs11172-018-2206-4},
number = {7},
pages = {1231--1240},
doi = {10.1007/s11172-018-2206-4}
}
MLA
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Nuraneeva, E. N., et al. “Cadmium(II) complexes with monoiodo- and dibromodipyrromethenes: synthesis, molecular structure, spectral-luminescent properties, and stability in solutions.” Russian Chemical Bulletin, vol. 67, no. 7, Jul. 2018, pp. 1231-1240. https://doi.org/10.1007%2Fs11172-018-2206-4.
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