Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes
Publication type: Journal Article
Publication date: 2018-11-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A new method for the synthesis of complexes PtIV(NHC)X4L (NHC is N-heterocyclic carbene of imidazole or benzimidazole series; X = Cl, Br; L is N-coordinated pyridine or NHC) based on mechanochemical oxidation of complexes PtII(NHC)X2L with dichloroiodobenzene (PhICl2) or pyridinium hydrobromide perbromide (PyHBr3) was proposed. Mechanochemical activation led to reduction in the synthesis time and increase in the selectivity of halogenation and yields of the target PtIV complexes (74–98%) as compared to the reaction in solutions.
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Total citations:
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Citations from 2024:
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(33%)
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Chikunov I. E. et al. Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes // Russian Chemical Bulletin. 2018. Vol. 67. No. 11. pp. 2003-2009.
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Chikunov I. E., Ranny G. S., Astakhov A. V., Tafeenko V. A., Chernyshev V. M. Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes // Russian Chemical Bulletin. 2018. Vol. 67. No. 11. pp. 2003-2009.
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RIS
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TY - JOUR
DO - 10.1007/s11172-018-2321-2
UR - https://doi.org/10.1007/s11172-018-2321-2
TI - Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes
T2 - Russian Chemical Bulletin
AU - Chikunov, I E
AU - Ranny, G S
AU - Astakhov, A V
AU - Tafeenko, V. A.
AU - Chernyshev, V M
PY - 2018
DA - 2018/11/01
PB - Springer Nature
SP - 2003-2009
IS - 11
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2018_Chikunov,
author = {I E Chikunov and G S Ranny and A V Astakhov and V. A. Tafeenko and V M Chernyshev},
title = {Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s11172-018-2321-2},
number = {11},
pages = {2003--2009},
doi = {10.1007/s11172-018-2321-2}
}
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MLA
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Chikunov, I. E., et al. “Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes.” Russian Chemical Bulletin, vol. 67, no. 11, Nov. 2018, pp. 2003-2009. https://doi.org/10.1007/s11172-018-2321-2.
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