Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate
Publication type: Journal Article
Publication date: 2018-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Allylation of norbornadiene with allyl formate in the presence of the palladium catalytic systems is characterized by several peculiarities associated with the new reaction route: hydroallylation (reductive allylation) occurs along with the traditional allylation (oxidative allylation). Both processes are considered from the single point of view, and the mechanism assuming different routes of the hydride transfer in the key intermediates was proposed. It was proved by using deuterated reactants that the hydride transfer can involve the allyl, norbornenyl, or formyl moieties. In all cases, the hydrogen atom bound to the carbon atom in the β-position relative to palladium is eliminated in this step.
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14
Total citations:
14
Citations from 2024:
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(14%)
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Durakov S. A. et al. Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate // Russian Chemical Bulletin. 2018. Vol. 67. No. 12. pp. 2234-2240.
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Durakov S. A., Shamsiev R. S., Flid V. R., Gekhman A. E. Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate // Russian Chemical Bulletin. 2018. Vol. 67. No. 12. pp. 2234-2240.
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RIS
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TY - JOUR
DO - 10.1007/s11172-018-2361-7
UR - https://doi.org/10.1007/s11172-018-2361-7
TI - Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate
T2 - Russian Chemical Bulletin
AU - Durakov, S A
AU - Shamsiev, R S
AU - Flid, V R
AU - Gekhman, A E
PY - 2018
DA - 2018/12/01
PB - Springer Nature
SP - 2234-2240
IS - 12
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2018_Durakov,
author = {S A Durakov and R S Shamsiev and V R Flid and A E Gekhman},
title = {Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-018-2361-7},
number = {12},
pages = {2234--2240},
doi = {10.1007/s11172-018-2361-7}
}
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MLA
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Durakov, S. A., et al. “Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate.” Russian Chemical Bulletin, vol. 67, no. 12, Dec. 2018, pp. 2234-2240. https://doi.org/10.1007/s11172-018-2361-7.