Russian Chemical Bulletin, volume 67, issue 12, pages 2234-2240

Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate

Publication typeJournal Article
Publication date2018-12-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.7
ISSN10665285, 15739171
General Chemistry
Abstract
Allylation of norbornadiene with allyl formate in the presence of the palladium catalytic systems is characterized by several peculiarities associated with the new reaction route: hydroallylation (reductive allylation) occurs along with the traditional allylation (oxidative allylation). Both processes are considered from the single point of view, and the mechanism assuming different routes of the hydride transfer in the key intermediates was proposed. It was proved by using deuterated reactants that the hydride transfer can involve the allyl, norbornenyl, or formyl moieties. In all cases, the hydrogen atom bound to the carbon atom in the β-position relative to palladium is eliminated in this step.

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Durakov S. A. et al. Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate // Russian Chemical Bulletin. 2018. Vol. 67. No. 12. pp. 2234-2240.
GOST all authors (up to 50) Copy
Durakov S. A., Shamsiev R. S., Flid V. R., Gekhman A. E. Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate // Russian Chemical Bulletin. 2018. Vol. 67. No. 12. pp. 2234-2240.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-018-2361-7
UR - https://doi.org/10.1007%2Fs11172-018-2361-7
TI - Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate
T2 - Russian Chemical Bulletin
AU - Durakov, S A
AU - Shamsiev, R S
AU - Flid, V R
AU - Gekhman, A E
PY - 2018
DA - 2018/12/01 00:00:00
PB - Springer Nature
SP - 2234-2240
IS - 12
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex Copy
@article{2018_Durakov
author = {S A Durakov and R S Shamsiev and V R Flid and A E Gekhman},
title = {Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007%2Fs11172-018-2361-7},
number = {12},
pages = {2234--2240},
doi = {10.1007/s11172-018-2361-7}
}
MLA
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MLA Copy
Durakov, S. A., et al. “Hydride transfer mechanism in the catalytic allylation of norbornadiene with allyl formate.” Russian Chemical Bulletin, vol. 67, no. 12, Dec. 2018, pp. 2234-2240. https://doi.org/10.1007%2Fs11172-018-2361-7.
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