Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole
Тип публикации: Journal Article
Дата публикации: 2019-02-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
A new method for the preparation of 2,3,4,5-tetraphenyl-1-octyl-1-monophosphole was developed. It was shown that the reaction of n-octyl chloride with a mixture of sodium 1,2,3-tri-and 1-monophospholides obtained by refluxing sodium polyphosphides with diphenylacetylene resulted in the formation of exclusively 1-n-octyl-1-monophosphole. The photophysical properties of 1-n-octyl-1-monophosphole were studied by electron absorption and emission spectroscopy. According to the Raman spectroscopy data, the phenyl moieties of this molecule are efficiently conjugated with the diene system of the heterocycle leading to the appearance of the corresponding absorption and emission bands in the visible spectral range.
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Petrov A. V. et al. Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole // Russian Chemical Bulletin. 2019. Vol. 68. No. 2. pp. 445-448.
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Petrov A. V., Zagidullin A. A., Burganov T. I., Shatalova N. I., Katsyuba S. A., Milyukov V. A. Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole // Russian Chemical Bulletin. 2019. Vol. 68. No. 2. pp. 445-448.
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TY - JOUR
DO - 10.1007/s11172-019-2406-6
UR - https://doi.org/10.1007/s11172-019-2406-6
TI - Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole
T2 - Russian Chemical Bulletin
AU - Petrov, A. V.
AU - Zagidullin, A A
AU - Burganov, T I
AU - Shatalova, N I
AU - Katsyuba, S A
AU - Milyukov, V. A.
PY - 2019
DA - 2019/02/01
PB - Springer Nature
SP - 445-448
IS - 2
VL - 68
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2019_Petrov,
author = {A. V. Petrov and A A Zagidullin and T I Burganov and N I Shatalova and S A Katsyuba and V. A. Milyukov},
title = {Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole},
journal = {Russian Chemical Bulletin},
year = {2019},
volume = {68},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11172-019-2406-6},
number = {2},
pages = {445--448},
doi = {10.1007/s11172-019-2406-6}
}
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Petrov, A. V., et al. “Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole.” Russian Chemical Bulletin, vol. 68, no. 2, Feb. 2019, pp. 445-448. https://doi.org/10.1007/s11172-019-2406-6.
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