Russian Chemical Bulletin, volume 69, issue 11, pages 2183-2190

Trifunctional thermosetting monomer with propargyl and phthalonitrile groups

Publication typeJournal Article
Publication date2020-11-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.7
ISSN10665285, 15739171
General Chemistry
Abstract
A new monomer containing thermosetting groups of two types, namely, propargyl ether and phthalonitrile, in the structure of the molecule was synthesized and studied. It was found that thermal polymerization was accompanied by the degradation of the monomer with propargyl ether decomposition. This problem can be solved using catalysts based on Cu(i) favoring the polymerization at both the propargyl group and phthalonitrile fragments. The cured monomer has a non-porous structure and high thermal properties (Vicat softening temperature 395 °C, T5% 451 °C). The low viscosity of the melt (<200 mPa s at 120 °C) and low glass-transition temperature (9 °C) of the monomer make it possible to use it for the formation of composite materials by vacuum infusion or injection into a mold.

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GOST Copy
Yakovlev M. V. et al. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
GOST all authors (up to 50) Copy
Yakovlev M. V., Morozov O. S., Afanaseva E. S., Bulgakov B. A., Babkin A., Kepman A., Avdeev V. V. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-020-3020-3
UR - https://doi.org/10.1007%2Fs11172-020-3020-3
TI - Trifunctional thermosetting monomer with propargyl and phthalonitrile groups
T2 - Russian Chemical Bulletin
AU - Yakovlev, M. V.
AU - Afanaseva, E S
AU - Kepman, A.V.
AU - Morozov, O S
AU - Avdeev, V V
AU - Bulgakov, B A
AU - Babkin, A.V.
PY - 2020
DA - 2020/11/01 00:00:00
PB - Springer Nature
SP - 2183-2190
IS - 11
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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BibTex Copy
@article{2020_Yakovlev
author = {M. V. Yakovlev and E S Afanaseva and A.V. Kepman and O S Morozov and V V Avdeev and B A Bulgakov and A.V. Babkin},
title = {Trifunctional thermosetting monomer with propargyl and phthalonitrile groups},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2Fs11172-020-3020-3},
number = {11},
pages = {2183--2190},
doi = {10.1007/s11172-020-3020-3}
}
MLA
Cite this
MLA Copy
Yakovlev, M. V., et al. “Trifunctional thermosetting monomer with propargyl and phthalonitrile groups.” Russian Chemical Bulletin, vol. 69, no. 11, Nov. 2020, pp. 2183-2190. https://doi.org/10.1007%2Fs11172-020-3020-3.
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