Russian Chemical Bulletin, volume 69, issue 11, pages 2183-2190
Trifunctional thermosetting monomer with propargyl and phthalonitrile groups
Yakovlev M. V.
1
,
Morozov O S
2
,
Afanaseva E S
2
,
Bulgakov B A
2
,
Babkin A.V.
2
,
Kepman A.V.
2
,
Avdeev V V
2
Publication type: Journal Article
Publication date: 2020-11-01
Journal:
Russian Chemical Bulletin
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Abstract
A new monomer containing thermosetting groups of two types, namely, propargyl ether and phthalonitrile, in the structure of the molecule was synthesized and studied. It was found that thermal polymerization was accompanied by the degradation of the monomer with propargyl ether decomposition. This problem can be solved using catalysts based on Cu(i) favoring the polymerization at both the propargyl group and phthalonitrile fragments. The cured monomer has a non-porous structure and high thermal properties (Vicat softening temperature 395 °C, T5% 451 °C). The low viscosity of the melt (<200 mPa s at 120 °C) and low glass-transition temperature (9 °C) of the monomer make it possible to use it for the formation of composite materials by vacuum infusion or injection into a mold.
Citations by journals
1
2
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Reactive and Functional Polymers
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Reactive and Functional Polymers
2 publications, 28.57%
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Polymer
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Polymer
2 publications, 28.57%
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Materials Today Communications
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Materials Today Communications
1 publication, 14.29%
|
Molecular Systems Design and Engineering
|
Molecular Systems Design and Engineering
1 publication, 14.29%
|
Polymers for Advanced Technologies
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Polymers for Advanced Technologies
1 publication, 14.29%
|
1
2
|
Citations by publishers
1
2
3
4
5
|
|
Elsevier
|
Elsevier
5 publications, 71.43%
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 14.29%
|
Wiley
|
Wiley
1 publication, 14.29%
|
1
2
3
4
5
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yakovlev M. V. et al. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
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Yakovlev M. V., Morozov O. S., Afanaseva E. S., Bulgakov B. A., Babkin A., Kepman A., Avdeev V. V. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
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TY - JOUR
DO - 10.1007/s11172-020-3020-3
UR - https://doi.org/10.1007%2Fs11172-020-3020-3
TI - Trifunctional thermosetting monomer with propargyl and phthalonitrile groups
T2 - Russian Chemical Bulletin
AU - Yakovlev, M. V.
AU - Afanaseva, E S
AU - Kepman, A.V.
AU - Morozov, O S
AU - Avdeev, V V
AU - Bulgakov, B A
AU - Babkin, A.V.
PY - 2020
DA - 2020/11/01 00:00:00
PB - Springer Nature
SP - 2183-2190
IS - 11
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2020_Yakovlev
author = {M. V. Yakovlev and E S Afanaseva and A.V. Kepman and O S Morozov and V V Avdeev and B A Bulgakov and A.V. Babkin},
title = {Trifunctional thermosetting monomer with propargyl and phthalonitrile groups},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2Fs11172-020-3020-3},
number = {11},
pages = {2183--2190},
doi = {10.1007/s11172-020-3020-3}
}
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MLA
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Yakovlev, M. V., et al. “Trifunctional thermosetting monomer with propargyl and phthalonitrile groups.” Russian Chemical Bulletin, vol. 69, no. 11, Nov. 2020, pp. 2183-2190. https://doi.org/10.1007%2Fs11172-020-3020-3.