Trifunctional thermosetting monomer with propargyl and phthalonitrile groups
Тип публикации: Journal Article
Дата публикации: 2020-11-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
A new monomer containing thermosetting groups of two types, namely, propargyl ether and phthalonitrile, in the structure of the molecule was synthesized and studied. It was found that thermal polymerization was accompanied by the degradation of the monomer with propargyl ether decomposition. This problem can be solved using catalysts based on Cu(i) favoring the polymerization at both the propargyl group and phthalonitrile fragments. The cured monomer has a non-porous structure and high thermal properties (Vicat softening temperature 395 °C, T5% 451 °C). The low viscosity of the melt (<200 mPa s at 120 °C) and low glass-transition temperature (9 °C) of the monomer make it possible to use it for the formation of composite materials by vacuum infusion or injection into a mold.
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Yakovlev M. V. et al. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
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Yakovlev M. V., Morozov O. S., Afanaseva E. S., Bulgakov B. A., Babkin A., Kepman A., Avdeev V. V. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups // Russian Chemical Bulletin. 2020. Vol. 69. No. 11. pp. 2183-2190.
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TY - JOUR
DO - 10.1007/s11172-020-3020-3
UR - http://link.springer.com/10.1007/s11172-020-3020-3
TI - Trifunctional thermosetting monomer with propargyl and phthalonitrile groups
T2 - Russian Chemical Bulletin
AU - Yakovlev, M. V.
AU - Morozov, O S
AU - Afanaseva, E S
AU - Bulgakov, B A
AU - Babkin, A.V.
AU - Kepman, A.V.
AU - Avdeev, V V
PY - 2020
DA - 2020/11/01
PB - Springer Nature
SP - 2183-2190
IS - 11
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2020_Yakovlev,
author = {M. V. Yakovlev and O S Morozov and E S Afanaseva and B A Bulgakov and A.V. Babkin and A.V. Kepman and V V Avdeev},
title = {Trifunctional thermosetting monomer with propargyl and phthalonitrile groups},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11172-020-3020-3},
number = {11},
pages = {2183--2190},
doi = {10.1007/s11172-020-3020-3}
}
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MLA
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Yakovlev, M. V., et al. “Trifunctional thermosetting monomer with propargyl and phthalonitrile groups.” Russian Chemical Bulletin, vol. 69, no. 11, Nov. 2020, pp. 2183-2190. http://link.springer.com/10.1007/s11172-020-3020-3.
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