A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine
Тип публикации: Journal Article
Дата публикации: 2020-12-29
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
A synthetic approach to a novel type of phosphonium and mixed phosphonium-iodonium ylides containing a conformationally fixed phosphonium fragment is developed. New representatives of these families of chemical compounds based on cyclic phenoxaphosphinine were synthesized. One compound was structurally characterized by single-crystal X-ray diffraction. Based on the 1H NMR data, one can state that phosphonium ylide exists in solution in the form of two geometric isomers even at room temperature. This is indicative of pronounced double-bond character of the bond between the ylide carbon atom and the stabilizing carbomethoxy group.
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Nenashev A. S. et al. A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine // Russian Chemical Bulletin. 2020. Vol. 69. No. 12. pp. 2333-2339.
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Nenashev A. S., Vinogradov D. S., Mironov A., Podrugina T. A. A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine // Russian Chemical Bulletin. 2020. Vol. 69. No. 12. pp. 2333-2339.
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TY - JOUR
DO - 10.1007/s11172-020-3034-x
UR - https://doi.org/10.1007/s11172-020-3034-x
TI - A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine
T2 - Russian Chemical Bulletin
AU - Nenashev, A S
AU - Vinogradov, D S
AU - Mironov, A.V.
AU - Podrugina, T A
PY - 2020
DA - 2020/12/29
PB - Springer Nature
SP - 2333-2339
IS - 12
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2020_Nenashev,
author = {A S Nenashev and D S Vinogradov and A.V. Mironov and T A Podrugina},
title = {A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-020-3034-x},
number = {12},
pages = {2333--2339},
doi = {10.1007/s11172-020-3034-x}
}
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MLA
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Nenashev, A. S., et al. “A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine.” Russian Chemical Bulletin, vol. 69, no. 12, Dec. 2020, pp. 2333-2339. https://doi.org/10.1007/s11172-020-3034-x.
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