Springer Nature
Russian Chemical Bulletin
,  том 70 ,  издание 4 ,  страницы 773-779

Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system

Тип публикации: Journal Article
Дата публикации: 2021-04-01
Springer Nature
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SJR: 0.272
CiteScore: 2.8
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
The structure of polymer chain of poly(1,3-pentadiene) synthesized via a stereospecific polymerization catalyzed by a system based on neodymium trichloride was determined using one-dimensional with a T2 filter and two-dimensional HMBC and HSQC 1H-13C NMR spectroscopic methods. It was found that the polymer chain of poly(1,3-pentadiene) consists of 1,4-trans-, 1,4-cis-, 1,2-trans-, and 1,2-cis-units. A new method was proposed for the quantitative calculation of content of the structural units in poly(1,3-pentadiene) possessing a mixed microstructure. Spectral signals of the carbon atoms of terminal units having 1,4-trans- and 1,4-cis-structures have been for the first time identified in the macromolecules of poly(1,3-pentadiene) synthesized via the stereospecific polymerization.
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Rozentsvet V. A. et al. Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system // Russian Chemical Bulletin. 2021. Vol. 70. No. 4. pp. 773-779.
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Rozentsvet V. A., Sablina N. A., Ulyanova D. M., Smirnov S. N., Tolstoy P. M. Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system // Russian Chemical Bulletin. 2021. Vol. 70. No. 4. pp. 773-779.
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TY - JOUR
DO - 10.1007/s11172-021-3150-2
UR - https://doi.org/10.1007/s11172-021-3150-2
TI - Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system
T2 - Russian Chemical Bulletin
AU - Rozentsvet, V A
AU - Sablina, N A
AU - Ulyanova, D M
AU - Smirnov, S. N.
AU - Tolstoy, P M
PY - 2021
DA - 2021/04/01
PB - Springer Nature
SP - 773-779
IS - 4
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2021_Rozentsvet,
author = {V A Rozentsvet and N A Sablina and D M Ulyanova and S. N. Smirnov and P M Tolstoy},
title = {Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-021-3150-2},
number = {4},
pages = {773--779},
doi = {10.1007/s11172-021-3150-2}
}
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Rozentsvet, V. A., et al. “Structure of the polymer chain of poly(1,3-pentadiene) synthesized using a stereospecific catalytic system.” Russian Chemical Bulletin, vol. 70, no. 4, Apr. 2021, pp. 773-779. https://doi.org/10.1007/s11172-021-3150-2.
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