Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction
Publication type: Journal Article
Publication date: 2021-07-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
New nickel(ii) complexes of the general formula LNi(Cp)X (L is an N-heterocyclic carbene (NHC) ligand of the 1,2,4-triazole or imidazole series; Cp is the cyclopentadienyl anion; X = Cl, I) are reported. In these complexes, the NHC ligands (L) contain an alkylamino group at the 3 or 4 position of the heterocycle. The synthesized complexes and structurally similar complexes without an alkylamino group were tested for catalytic activity in the Suzuki—Miyaura reaction. The introduction of an alkylamino group into the NHC ligand leads to the enhancement of the catalytic activity of complexes with N,N′-diaryl-substituted NHC ligands of the imidazole series and a decrease in the activity of the complexes with N,N′-dialkyl-substituted NHC ligands of the 1,2,4-triazole series.
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Chesnokov V. V. et al. Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction // Russian Chemical Bulletin. 2021. Vol. 70. No. 7. pp. 1281-1289.
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Chesnokov V. V., SHEVCHENKO M. A., Soliev S. B., Tafeenko V. A., Chernyshev V. M. Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction // Russian Chemical Bulletin. 2021. Vol. 70. No. 7. pp. 1281-1289.
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TY - JOUR
DO - 10.1007/s11172-021-3212-5
UR - https://doi.org/10.1007/s11172-021-3212-5
TI - Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction
T2 - Russian Chemical Bulletin
AU - Chesnokov, V. V.
AU - SHEVCHENKO, M. A.
AU - Soliev, S B
AU - Tafeenko, V. A.
AU - Chernyshev, V M
PY - 2021
DA - 2021/07/01
PB - Springer Nature
SP - 1281-1289
IS - 7
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2021_Chesnokov,
author = {V. V. Chesnokov and M. A. SHEVCHENKO and S B Soliev and V. A. Tafeenko and V M Chernyshev},
title = {Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/s11172-021-3212-5},
number = {7},
pages = {1281--1289},
doi = {10.1007/s11172-021-3212-5}
}
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MLA
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Chesnokov, V. V., et al. “Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction.” Russian Chemical Bulletin, vol. 70, no. 7, Jul. 2021, pp. 1281-1289. https://doi.org/10.1007/s11172-021-3212-5.