Russian Chemical Bulletin, volume 71, issue 2, pages 283-291
Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate
Kuz'mina L. G.
1
,
Publication type: Journal Article
Publication date: 2022-02-01
Journal:
Russian Chemical Bulletin
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Abstract
Norleucine peroxosolvate 2Nle · 3H2O2 was studied by single-crystal X-ray diffraction. There are 16 crystallographically independent amino acid molecules and 24 hydrogen peroxide molecules per asymmetric unit of the crystal structure. The crystal packing of this compounds is typical of mesomorphic crystals. The loose layers of aliphatic moieties alternate with double layers formed by the functional groups of all structural units of the crystal through O-H⋯O or N-H⋯O hydrogen bonds. Some amino acid and hydrogen peroxide molecules are disordered. The character of disorder is considered in terms of frozen dynamics, which suggests the possible mechanism of the involvement of hydrogen peroxide in the transport of bulky natural molecules across cell membranes.
Citations by journals
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Crystal Growth and Design
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 33.33%
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Springer Nature
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Springer Nature
1 publication, 33.33%
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Elsevier
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Elsevier
1 publication, 33.33%
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1
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Kuz'mina L. G., Churakov A. Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate // Russian Chemical Bulletin. 2022. Vol. 71. No. 2. pp. 283-291.
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Kuz'mina L. G., Churakov A. Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate // Russian Chemical Bulletin. 2022. Vol. 71. No. 2. pp. 283-291.
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TY - JOUR
DO - 10.1007/s11172-022-3409-2
UR - https://doi.org/10.1007%2Fs11172-022-3409-2
TI - Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate
T2 - Russian Chemical Bulletin
AU - Kuz'mina, L. G.
AU - Churakov, A.V.
PY - 2022
DA - 2022/02/01 00:00:00
PB - Springer Nature
SP - 283-291
IS - 2
VL - 71
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2022_Kuz'mina,
author = {L. G. Kuz'mina and A.V. Churakov},
title = {Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate},
journal = {Russian Chemical Bulletin},
year = {2022},
volume = {71},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007%2Fs11172-022-3409-2},
number = {2},
pages = {283--291},
doi = {10.1007/s11172-022-3409-2}
}
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Kuz'mina, L. G., and A.V. Churakov. “Crystal structure of amino acid peroxosolvates; X-ray diffraction study of norleucine peroxosolvate.” Russian Chemical Bulletin, vol. 71, no. 2, Feb. 2022, pp. 283-291. https://doi.org/10.1007%2Fs11172-022-3409-2.
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