Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds
Publication type: Journal Article
Publication date: 2022-04-25
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Cationic polymerization of penta-1,3-diene with catalytic systems based on organoaluminum compounds (AlEtCl2, AlEt2Cl, and AlEt3) in combination with isopropyl chloride makes it possible to synthesize completely soluble solid polymers in a high yield with the softening point in the range from 81 to 91 °C. The signals of carbon atoms of the head isopropyl groups connected with 1,4-trans-unit of polypentadiene were identified using 1H and 13C NMR spectroscopy with the T2 filter, as well as 1H, 13C HSQC and HMBC 2D NMR spectroscopy.
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Rozentsvet V. A. et al. Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds // Russian Chemical Bulletin. 2022. Vol. 71. No. 4. pp. 787-795.
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Rozentsvet V. A., Ulyanova D. M., Sablina N. A., Kuznetsova M. G., Tolstoy P. M. Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds // Russian Chemical Bulletin. 2022. Vol. 71. No. 4. pp. 787-795.
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TY - JOUR
DO - 10.1007/s11172-022-3479-1
UR - https://doi.org/10.1007/s11172-022-3479-1
TI - Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds
T2 - Russian Chemical Bulletin
AU - Rozentsvet, V A
AU - Ulyanova, D M
AU - Sablina, N A
AU - Kuznetsova, M G
AU - Tolstoy, P M
PY - 2022
DA - 2022/04/25
PB - Springer Nature
SP - 787-795
IS - 4
VL - 71
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2022_Rozentsvet,
author = {V A Rozentsvet and D M Ulyanova and N A Sablina and M G Kuznetsova and P M Tolstoy},
title = {Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds},
journal = {Russian Chemical Bulletin},
year = {2022},
volume = {71},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-022-3479-1},
number = {4},
pages = {787--795},
doi = {10.1007/s11172-022-3479-1}
}
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MLA
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Rozentsvet, V. A., et al. “Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds.” Russian Chemical Bulletin, vol. 71, no. 4, Apr. 2022, pp. 787-795. https://doi.org/10.1007/s11172-022-3479-1.
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