volume 72 issue 4 pages 895-901

Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides

E M Zhilina 1
A S Russkih 1
T V Osinkina 1
E V Ignatieva 1
S. A. Petrova 1
S A Krasikov 1
A V Dolmatov 1
A A Rempel' 1
Publication typeJournal Article
Publication date2023-04-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
We consider a new method for the preparation of refractory high-entropy alloys (HEAs) AlTiZrVNb, which consists in the joint aluminothermic reduction of metals from their oxides. It was determined that V and Nb undergo reduction to a greater extent, and about 90% of their amounts transfer into the metal phase. Metals Ti and Zr undergo reduction to a lesser extent, with 76 and 50% of their amounts transitioning into the metal phase, respectively. The obtained alloy has a multiphase structure consisting of C14 Laves phases, Zr5Al3-type phases, and a B2-type ordered phase, which plays the role of a matrix. The microhardness of the alloy is 6.37 GPa, which is similar to the values of refractory HEAs. The structure of the obtained alloy has a similar structure throughout its bulk, namely, coarse-grained with a number of pores, partly filled with non-metallic inclusions of aluminum oxide.
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Zhilina E. M. et al. Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides // Russian Chemical Bulletin. 2023. Vol. 72. No. 4. pp. 895-901.
GOST all authors (up to 50) Copy
Zhilina E. M., Russkih A. S., Osinkina T. V., Ignatieva E. V., Petrova S. A., Krasikov S. A., Dolmatov A. V., Rempel' A. A. Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides // Russian Chemical Bulletin. 2023. Vol. 72. No. 4. pp. 895-901.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-023-3852-7
UR - https://doi.org/10.1007/s11172-023-3852-7
TI - Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides
T2 - Russian Chemical Bulletin
AU - Zhilina, E M
AU - Russkih, A S
AU - Osinkina, T V
AU - Ignatieva, E V
AU - Petrova, S. A.
AU - Krasikov, S A
AU - Dolmatov, A V
AU - Rempel', A A
PY - 2023
DA - 2023/04/01
PB - Springer Nature
SP - 895-901
IS - 4
VL - 72
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Zhilina,
author = {E M Zhilina and A S Russkih and T V Osinkina and E V Ignatieva and S. A. Petrova and S A Krasikov and A V Dolmatov and A A Rempel'},
title = {Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides},
journal = {Russian Chemical Bulletin},
year = {2023},
volume = {72},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-023-3852-7},
number = {4},
pages = {895--901},
doi = {10.1007/s11172-023-3852-7}
}
MLA
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MLA Copy
Zhilina, E. M., et al. “Possibility of obtaining refractory high-entropy AlTiZrVNb alloys from metal oxides.” Russian Chemical Bulletin, vol. 72, no. 4, Apr. 2023, pp. 895-901. https://doi.org/10.1007/s11172-023-3852-7.
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