Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid
Publication type: Journal Article
Publication date: 2023-10-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The stereoselective synthesis of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid was carried out using Ti-catalyzed homo-cyclomagnesiation of 2-(hepta-5,6-dien-1-yloxy)tetrahydro-2H-pyran. Intermolecular esterification of this dicarboxylic acid with polyether acetylenic alcohols in the presence of carbodiimides was used to synthesize the corresponding monoesters and symmetric diesters. Using the intramolecular oxidative coupling of terminal triple bonds of the latter compounds, polyether macrodiolides containing 1Z,5Z-diene and 1,3-diyne fragments were synthesized.
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Islamov I. I. et al. Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid // Russian Chemical Bulletin. 2023. Vol. 72. No. 10. pp. 2473-2483.
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Islamov I. I., Yusupova A. V., Dyakonov V. A., Dzhemilev U. M. Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid // Russian Chemical Bulletin. 2023. Vol. 72. No. 10. pp. 2473-2483.
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TY - JOUR
DO - 10.1007/s11172-023-4049-x
UR - https://doi.org/10.1007/s11172-023-4049-x
TI - Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid
T2 - Russian Chemical Bulletin
AU - Islamov, I I
AU - Yusupova, A. V.
AU - Dyakonov, V A
AU - Dzhemilev, U M
PY - 2023
DA - 2023/10/01
PB - Springer Nature
SP - 2473-2483
IS - 10
VL - 72
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2023_Islamov,
author = {I I Islamov and A. V. Yusupova and V A Dyakonov and U M Dzhemilev},
title = {Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid},
journal = {Russian Chemical Bulletin},
year = {2023},
volume = {72},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007/s11172-023-4049-x},
number = {10},
pages = {2473--2483},
doi = {10.1007/s11172-023-4049-x}
}
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MLA
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Islamov, I. I., et al. “Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid.” Russian Chemical Bulletin, vol. 72, no. 10, Oct. 2023, pp. 2473-2483. https://doi.org/10.1007/s11172-023-4049-x.