volume 72 issue 10 pages 2473-2483

Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid

Publication typeJournal Article
Publication date2023-10-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
The stereoselective synthesis of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid was carried out using Ti-catalyzed homo-cyclomagnesiation of 2-(hepta-5,6-dien-1-yloxy)tetrahydro-2H-pyran. Intermolecular esterification of this dicarboxylic acid with polyether acetylenic alcohols in the presence of carbodiimides was used to synthesize the corresponding monoesters and symmetric diesters. Using the intramolecular oxidative coupling of terminal triple bonds of the latter compounds, polyether macrodiolides containing 1Z,5Z-diene and 1,3-diyne fragments were synthesized.
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Islamov I. I. et al. Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid // Russian Chemical Bulletin. 2023. Vol. 72. No. 10. pp. 2473-2483.
GOST all authors (up to 50) Copy
Islamov I. I., Yusupova A. V., Dyakonov V. A., Dzhemilev U. M. Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid // Russian Chemical Bulletin. 2023. Vol. 72. No. 10. pp. 2473-2483.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-023-4049-x
UR - https://doi.org/10.1007/s11172-023-4049-x
TI - Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid
T2 - Russian Chemical Bulletin
AU - Islamov, I I
AU - Yusupova, A. V.
AU - Dyakonov, V A
AU - Dzhemilev, U M
PY - 2023
DA - 2023/10/01
PB - Springer Nature
SP - 2473-2483
IS - 10
VL - 72
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Islamov,
author = {I I Islamov and A. V. Yusupova and V A Dyakonov and U M Dzhemilev},
title = {Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid},
journal = {Russian Chemical Bulletin},
year = {2023},
volume = {72},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007/s11172-023-4049-x},
number = {10},
pages = {2473--2483},
doi = {10.1007/s11172-023-4049-x}
}
MLA
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MLA Copy
Islamov, I. I., et al. “Synthesis of polyether macrodiolides based on acetylenic derivatives of (5Z,9Z)-tetradeca-5,9-diene-1,14-dioic acid.” Russian Chemical Bulletin, vol. 72, no. 10, Oct. 2023, pp. 2473-2483. https://doi.org/10.1007/s11172-023-4049-x.