Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety
Publication type: Journal Article
Publication date: 2024-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
Abstract
A stereoselective synthesis of new (6Z,10Z)-16-hydroxyhexadeca-6,10-dienoic and (7Z,11Z)-18-hydroxyoctadeca-7,11-dienoic acid that involved the Ti-catalyzed homocyclomagnesiation of the functionally substituted 1,2-dienes was developed. Subsequent intramolecular cyclization of the synthesized ω-hydroxyalkadienoic acids in the presence of catalytic amounts (2.5–10 mol.%) of hafnium(iv) triflate gave unsaturated macrocyclic lactones and diolides with pharmacophoric 1Z,5Z-diene moieties.
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Islamov I. I. et al. Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety // Russian Chemical Bulletin. 2024. Vol. 73. No. 6. pp. 1623-1630.
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Islamov I. I., Gaisin I. V., Dzhemilev U. M., Dyakonov V. A. Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety // Russian Chemical Bulletin. 2024. Vol. 73. No. 6. pp. 1623-1630.
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TY - JOUR
DO - 10.1007/s11172-024-4278-7
UR - https://link.springer.com/10.1007/s11172-024-4278-7
TI - Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety
T2 - Russian Chemical Bulletin
AU - Islamov, I I
AU - Gaisin, I. V.
AU - Dzhemilev, U M
AU - Dyakonov, V A
PY - 2024
DA - 2024/06/01
PB - Springer Nature
SP - 1623-1630
IS - 6
VL - 73
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2024_Islamov,
author = {I I Islamov and I. V. Gaisin and U M Dzhemilev and V A Dyakonov},
title = {Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety},
journal = {Russian Chemical Bulletin},
year = {2024},
volume = {73},
publisher = {Springer Nature},
month = {jun},
url = {https://link.springer.com/10.1007/s11172-024-4278-7},
number = {6},
pages = {1623--1630},
doi = {10.1007/s11172-024-4278-7}
}
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MLA
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Islamov, I. I., et al. “Synthesis of macrocyclic mono- and diolides based on new ω-hydroxyalkadienoic acids with (Z,Z)-1,5-diene moiety.” Russian Chemical Bulletin, vol. 73, no. 6, Jun. 2024, pp. 1623-1630. https://link.springer.com/10.1007/s11172-024-4278-7.