Springer Nature
Russian Chemical Bulletin
,  volume 73 ,  issue 7 ,  pages 1900-1906

Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system

Publication type: Journal Article
Publication date: 2024-07-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
Abstract
The reactions of 1-alkynylphosphines with Et2Zn in the presence of catalytic amounts of Cp2ZrCl2 and EtMgBr proceed regio- and stereoselectively to afford (1Z)-alkenylphosphines. The oxidation and sulfonation of synthesized 1-alkenylphosphines with an aqueous solution of hydrogen peroxide or elemental sulfur give (1Z)-alkenylphosphine oxides and (1Z)-alkenylphosphine sulfides, respectively. A plausible scheme for the Zr—Mg-catalyzed 2-zincoethylzincation of 1-alkynylphosphines was proposed.
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Gabdullin A. M. et al. Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system // Russian Chemical Bulletin. 2024. Vol. 73. No. 7. pp. 1900-1906.
GOST all authors (up to 50) Copy
Gabdullin A. M., Kadikova R. N., Mozgovoj O. S., Ramazanov I. R. Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system // Russian Chemical Bulletin. 2024. Vol. 73. No. 7. pp. 1900-1906.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-024-4307-6
UR - https://link.springer.com/10.1007/s11172-024-4307-6
TI - Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system
T2 - Russian Chemical Bulletin
AU - Gabdullin, A. M.
AU - Kadikova, R N
AU - Mozgovoj, O. S.
AU - Ramazanov, I R
PY - 2024
DA - 2024/07/01
PB - Springer Nature
SP - 1900-1906
IS - 7
VL - 73
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Gabdullin,
author = {A. M. Gabdullin and R N Kadikova and O. S. Mozgovoj and I R Ramazanov},
title = {Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system},
journal = {Russian Chemical Bulletin},
year = {2024},
volume = {73},
publisher = {Springer Nature},
month = {jul},
url = {https://link.springer.com/10.1007/s11172-024-4307-6},
number = {7},
pages = {1900--1906},
doi = {10.1007/s11172-024-4307-6}
}
MLA
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MLA Copy
Gabdullin, A. M., et al. “Reactions of substituted 1-alkynylphosphines with Et2Zn catalyzed by the Cp2ZrCl2—EtMgBr system.” Russian Chemical Bulletin, vol. 73, no. 7, Jul. 2024, pp. 1900-1906. https://link.springer.com/10.1007/s11172-024-4307-6.