Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene
N A Protasenko
1
,
A I Poddelsky
1
Publication type: Journal Article
Publication date: 2020-11-26
scimago Q3
wos Q4
SJR: 0.238
CiteScore: 1.5
Impact factor: 0.9
ISSN: 00405760, 1573935X
General Chemistry
Abstract
New heteroligand cobalt(II), iron(II), and manganese(II) complexes of the M(3,6-SQ)2L type bearing 3,6-di-tert-butyl-o-benzosemiquinonato ligands (3,6-SQ) and 2,2'-biquinoline or 1,4-di-tert-butyl-1,4-diazabutadiene-1,3 as neutral ligands (L) have been synthesized and characterized. It was shown on the basis of the magnetic susceptibility measurements and spectroscopic studies that all complexes contain metal(II) ions in the high-spin state and two radical-anionic o-semiquinonato ligands. It was found in the result of analysis of magnetic susceptibility temperature dependence by magnetic coupling parameters modeling that the antiferromagnetic ligand-ligand coupling takes place in the cobalt(II) and iron(II) complexes, while antiferromagnetic metal-ligand interactions dominate in the manganese(II) complexes.
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Protasenko N. A., Poddelsky A. I. Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene // Theoretical and Experimental Chemistry. 2020. Vol. 56. No. 5. pp. 338-345.
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Protasenko N. A., Poddelsky A. I. Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene // Theoretical and Experimental Chemistry. 2020. Vol. 56. No. 5. pp. 338-345.
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TY - JOUR
DO - 10.1007/s11237-020-09663-1
UR - https://doi.org/10.1007/s11237-020-09663-1
TI - Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene
T2 - Theoretical and Experimental Chemistry
AU - Protasenko, N A
AU - Poddelsky, A I
PY - 2020
DA - 2020/11/26
PB - Springer Nature
SP - 338-345
IS - 5
VL - 56
SN - 0040-5760
SN - 1573-935X
ER -
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@article{2020_Protasenko,
author = {N A Protasenko and A I Poddelsky},
title = {Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene},
journal = {Theoretical and Experimental Chemistry},
year = {2020},
volume = {56},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s11237-020-09663-1},
number = {5},
pages = {338--345},
doi = {10.1007/s11237-020-09663-1}
}
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Protasenko, N. A., and A I Poddelsky. “Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene.” Theoretical and Experimental Chemistry, vol. 56, no. 5, Nov. 2020, pp. 338-345. https://doi.org/10.1007/s11237-020-09663-1.
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