A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst
Publication type: Journal Article
Publication date: 2005-10-01
scimago Q3
wos Q3
SJR: 0.240
CiteScore: 3.0
Impact factor: 1.7
ISSN: 03404285, 1572901X
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
Abstract
The reaction of bromate ion with malic acid in aqueous H2SO4 catalyzed by a tetraazamacrocyclic copper(II) complex exhibits oscillatory behavior. This complex contains an unsaturated macrocyclic ligand, 5,7,7,12,14,14-hexemethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. The reactions were monitored both spectrophotometrically and potentiometrically. It was found that the oscillation period (tp) is dependent on the initial concentrations of malic acid or H2SO4 but is independent of the initial concentrations of NaBrO3. The experimental results indicate that acrylonitrile, H2O2, vitamin C, glucose or CCl4 present in the system can inhibit the oscillations. A tentative mechanism is proposed.
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Total citations:
14
Citations from 2024:
1
(7.14%)
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GOST
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Hu G. et al. A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst // Transition Metal Chemistry. 2005. Vol. 30. No. 7. pp. 856-860.
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Hu G., Zhang Z. D., Lin H., Song J. M. A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst // Transition Metal Chemistry. 2005. Vol. 30. No. 7. pp. 856-860.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11243-005-6259-5
UR - https://doi.org/10.1007/s11243-005-6259-5
TI - A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst
T2 - Transition Metal Chemistry
AU - Hu, Gang
AU - Zhang, Zu De
AU - Lin, Hu
AU - Song, Ji Mei
PY - 2005
DA - 2005/10/01
PB - Springer Nature
SP - 856-860
IS - 7
VL - 30
SN - 0340-4285
SN - 1572-901X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Hu,
author = {Gang Hu and Zu De Zhang and Hu Lin and Ji Mei Song},
title = {A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst},
journal = {Transition Metal Chemistry},
year = {2005},
volume = {30},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007/s11243-005-6259-5},
number = {7},
pages = {856--860},
doi = {10.1007/s11243-005-6259-5}
}
Cite this
MLA
Copy
Hu, Gang, et al. “A New Oscillating Reaction of the Belousov-Zhabotinskii-type with a Macrocyclic Copper(II) Complex as Catalyst.” Transition Metal Chemistry, vol. 30, no. 7, Oct. 2005, pp. 856-860. https://doi.org/10.1007/s11243-005-6259-5.