Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media
Publication type: Journal Article
Publication date: 2018-11-07
scimago Q3
wos Q3
SJR: 0.240
CiteScore: 3.0
Impact factor: 1.7
ISSN: 03404285, 1572901X
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
Abstract
A series of 2-hydroxyethyl-substituted N-heterocyclic carbene–(NHC)PdX2PPh3 complexes have been synthesized by substitution of the pyridine or 3-chloropyridine ligand in (NHC)PdX2(pyridine/3-chloropyridine) complexes with triphenylphosphine. The new complexes were characterized by 1H, 13C {1H}, 31P {1H}NMR, FTIR spectroscopy and elemental analysis. Also, the molecular and crystal structures of 1c and 1d have been obtained by single-crystal X-ray diffraction. The 2-hydroxyethyl-substituted (NHC)PdX2PPh3 complexes have been examined as catalysts for the Sonogashira cross-coupling reaction in water/DMF solvent mixtures.
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Total citations:
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Citations from 2024:
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GOST
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Aktas A. et al. Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media // Transition Metal Chemistry. 2018. Vol. 44. No. 3. pp. 229-236.
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Aktas A., Erdemir F., Barut Celepci D., Gok Y., Aygün M. Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media // Transition Metal Chemistry. 2018. Vol. 44. No. 3. pp. 229-236.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11243-018-0286-5
UR - https://doi.org/10.1007/s11243-018-0286-5
TI - Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media
T2 - Transition Metal Chemistry
AU - Aktas, Aydin
AU - Erdemir, Fatoş
AU - Barut Celepci, Duygu
AU - Gok, Yetkin
AU - Aygün, Muhittin
PY - 2018
DA - 2018/11/07
PB - Springer Nature
SP - 229-236
IS - 3
VL - 44
SN - 0340-4285
SN - 1572-901X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Aktas,
author = {Aydin Aktas and Fatoş Erdemir and Duygu Barut Celepci and Yetkin Gok and Muhittin Aygün},
title = {Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media},
journal = {Transition Metal Chemistry},
year = {2018},
volume = {44},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s11243-018-0286-5},
number = {3},
pages = {229--236},
doi = {10.1007/s11243-018-0286-5}
}
Cite this
MLA
Copy
Aktas, Aydin, et al. “Mixed phosphine/N-heterocyclic carbene–palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media.” Transition Metal Chemistry, vol. 44, no. 3, Nov. 2018, pp. 229-236. https://doi.org/10.1007/s11243-018-0286-5.