Divergent synthesis of aryl amines and dihydroquinazolinones via electrochemistry-enabled rhodium-catalyzed C–H functionalization

Yi Kang Xing ¹

Zhen Hua Wang ¹

Ping Fang ¹

Cong Ma ¹

Tian-Sheng Mei ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Shanghai, China

University of Chinese Academy of Sciences

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Publication type: Journal Article

Publication date: 2023-06-12

Springer Nature

Science China Chemistry

scimago Q1

wos Q1

SJR: 2.377

CiteScore: 13.8

Impact factor: 9.7

ISSN: 16747291, 18691870

DOI: 10.1007/s11426-023-1603-9

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General Chemistry

Abstract

Electrochemistry-enabled rhodium-catalyzed C–H amination and amination cyclization of arene assisted by a weakly coordinating amide have been reported. Additionally, aryl amines and dihydroquinazolinones could be obtained selectively by controlling the electric current. Mechanistic studies suggested that the amination reaction likely involves an electrochemical oxidation-induced reductive elimination of a high valent rhodium intermediate, which led to the amination reaction even proceeding smoothly at room temperature.

Found

1 citation

Budnikova Yulia

DSc in Chemistry, professor

259 publications, 4 500 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

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GOST |

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GOST Copy

Xing Y. K. et al. Divergent synthesis of aryl amines and dihydroquinazolinones via electrochemistry-enabled rhodium-catalyzed C–H functionalization // Science China Chemistry. 2023.

GOST all authors (up to 50) Copy

Xing Y. K., Wang Z. H., Fang P., Ma C., Mei T. Divergent synthesis of aryl amines and dihydroquinazolinones via electrochemistry-enabled rhodium-catalyzed C–H functionalization // Science China Chemistry. 2023.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1007/s11426-023-1603-9

UR - https://doi.org/10.1007/s11426-023-1603-9

TI - Divergent synthesis of aryl amines and dihydroquinazolinones via electrochemistry-enabled rhodium-catalyzed C–H functionalization

T2 - Science China Chemistry

AU - Xing, Yi Kang

AU - Wang, Zhen Hua

AU - Fang, Ping

AU - Ma, Cong

AU - Mei, Tian-Sheng

PY - 2023

DA - 2023/06/12

PB - Springer Nature

SN - 1674-7291

SN - 1869-1870

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2023_Xing,

author = {Yi Kang Xing and Zhen Hua Wang and Ping Fang and Cong Ma and Tian-Sheng Mei},

title = {Divergent synthesis of aryl amines and dihydroquinazolinones via electrochemistry-enabled rhodium-catalyzed C–H functionalization},

journal = {Science China Chemistry},

year = {2023},

publisher = {Springer Nature},

month = {jun},

url = {https://doi.org/10.1007/s11426-023-1603-9},

doi = {10.1007/s11426-023-1603-9}

}

Publisher

Springer Nature

Journal

Science China Chemistry

scimago Q1

wos Q1

SJR

2.377

CiteScore

13.8

Impact factor

9.7

ISSN

16747291 (Print)

18691870 (Electronic)