volume 3 issue 1 pages 41-46

Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO

Publication typeJournal Article
Publication date2008-01-18
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ISSN16733495, 16733614
General Chemistry
Abstract
Controlled/living photopolymerization of methyl methacrylate (MMA) in miniemulsion mediated by 4-hydroxy-2,2,6,6-tetramethyl-piperidinyloxy (HTEMPO) was carried out at ambient temperatures. MMA miniemulsion was prepared by using an anionic surfactant with cetylalcohol as a co-stabilizer. The photopolymerization led to stable lattices and they were obtained with no coagulation during synthesis and no destabilization over time. It was found that the obtained MMA homopolymers exhibited relatively narrow molecular weight distribution (PDI = 1.27 − 1.36) which was characterized by GPC. The plots of number-average molecular weight in (M n) vs. conversion and ln([M0]/[M]) vs. time both were linear indicating that the reaction was a controlled/living free radical polymerization.
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Liu X., Jing Y., Bai Y. Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO // Frontiers of Chemistry in China. 2008. Vol. 3. No. 1. pp. 41-46.
GOST all authors (up to 50) Copy
Liu X., Jing Y., Bai Y. Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO // Frontiers of Chemistry in China. 2008. Vol. 3. No. 1. pp. 41-46.
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TY - JOUR
DO - 10.1007/s11458-008-0021-4
UR - http://link.springer.com/10.1007/s11458-008-0021-4
TI - Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO
T2 - Frontiers of Chemistry in China
AU - Liu, Xiaoxuan
AU - Jing, Yanni
AU - Bai, Yingkun
PY - 2008
DA - 2008/01/18
PB - Springer Nature
SP - 41-46
IS - 1
VL - 3
SN - 1673-3495
SN - 1673-3614
ER -
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BibTex (up to 50 authors) Copy
@article{2008_Liu,
author = {Xiaoxuan Liu and Yanni Jing and Yingkun Bai},
title = {Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO},
journal = {Frontiers of Chemistry in China},
year = {2008},
volume = {3},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1007/s11458-008-0021-4},
number = {1},
pages = {41--46},
doi = {10.1007/s11458-008-0021-4}
}
MLA
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MLA Copy
Liu, Xiaoxuan, et al. “Controlled/living photopolymerization of methyl methacrylate in miniemulsion mediated by HTEMPO.” Frontiers of Chemistry in China, vol. 3, no. 1, Jan. 2008, pp. 41-46. http://link.springer.com/10.1007/s11458-008-0021-4.