Ionics, volume 24, issue 6, pages 1685-1692

Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents

Publication typeJournal Article
Publication date2017-11-16
Journal: Ionics
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor2.8
ISSN09477047, 18620760
General Chemical Engineering
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
The Nafion-117 membranes in the Li+ form with pore-intercalated aprotonic organic solvents were prepared. The prepared materials were characterized by IR, impedance, and 7Li NMR spectroscopy. The solvent uptake of the membranes is shown to be controlled by the composition of organic solvents and their mixtures as well as by the conditions of the preliminary treatment of the initial membranes. For the Nafion-117 membrane, the degree of solvation can be improved by the preliminary treatment with alcohols, especially by the thermal treatment in methanol. Conductivity of the membranes is shown to increase with increasing content of the sorbed solvents. The best conductivity at 25 °C (2.5 × 10−3 and 1.6 × 10−3 S cm−1) was attained for the electrolytes based on the Nafion-117 membrane in lithium form with sorbed ethylene carbonate-propylene carbonate and ethylene carbonate-dimethoxyethane mixtures, respectively.

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Voropaeva D. Yu. et al. Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents // Ionics. 2017. Vol. 24. No. 6. pp. 1685-1692.
GOST all authors (up to 50) Copy
Voropaeva D. Yu., Novikova S. A., Kulova T. L., Yaroslavtsev A. B. Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents // Ionics. 2017. Vol. 24. No. 6. pp. 1685-1692.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11581-017-2333-1
UR - http://link.springer.com/10.1007/s11581-017-2333-1
TI - Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents
T2 - Ionics
AU - Voropaeva, D Yu
AU - Novikova, S. A.
AU - Yaroslavtsev, A. B.
AU - Kulova, T. L.
PY - 2017
DA - 2017/11/16 00:00:00
PB - Springer Nature
SP - 1685-1692
IS - 6
VL - 24
SN - 0947-7047
SN - 1862-0760
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Voropaeva,
author = {D Yu Voropaeva and S. A. Novikova and A. B. Yaroslavtsev and T. L. Kulova},
title = {Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents},
journal = {Ionics},
year = {2017},
volume = {24},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11581-017-2333-1},
number = {6},
pages = {1685--1692},
doi = {10.1007/s11581-017-2333-1}
}
MLA
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MLA Copy
Voropaeva, D. Yu., et al. “Conductivity of Nafion-117 membranes intercalated by polar aprotonic solvents.” Ionics, vol. 24, no. 6, Nov. 2017, pp. 1685-1692. http://link.springer.com/10.1007/s11581-017-2333-1.
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