Ionics, volume 24, issue 11, pages 3305-3315
Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics
Yuan Li
1
,
Tiantian Yang
1
,
Weiwei Wu
1
,
Zhenzhu Cao
1
,
Weiyan He
1
,
Yanfang Gao
1
,
Jinrong Liu
1
,
Guorong Li
2
Publication type: Journal Article
Publication date: 2018-03-03
General Chemical Engineering
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
Al-Mo codoped Li7La3Zr2O12 ceramics with fine grain were prepared by sol-gel method. The influences of Al-Mo codoping on the structure, microstructure, and conductivity of Li7La3Zr2O12 were investigated by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), and impedance spectroscopy. The cubic phase Li7La3Zr2O12 has been stabilized by partial substitution of Al for Li and Mo for Zr. Li6.6-3yAlyLa3Zr1.8Mo0.2O12 (0 ≤ y ≤ 0.1) has been sintered at 1040–1060 °C for 3 h. The liquid sintering facilitated its densification. The relative density of the composition with x = 0.075 was approximately 96.4%. Results indicated that the Al-Mo codoped LLZO synthesized by sol-gel method effectively lowered its sintering temperature, accelerated densification, and improved the ionic conductivity.
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Li Y. et al. Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics // Ionics. 2018. Vol. 24. No. 11. pp. 3305-3315.
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Li Y., Yang T., Wu W., Cao Z., He W., Gao Y., Liu J., Li G. Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics // Ionics. 2018. Vol. 24. No. 11. pp. 3305-3315.
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TY - JOUR
DO - 10.1007/s11581-018-2497-3
UR - https://doi.org/10.1007/s11581-018-2497-3
TI - Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics
T2 - Ionics
AU - Li, Yuan
AU - Yang, Tiantian
AU - Wu, Weiwei
AU - Cao, Zhenzhu
AU - He, Weiyan
AU - Gao, Yanfang
AU - Liu, Jinrong
AU - Li, Guorong
PY - 2018
DA - 2018/03/03 00:00:00
PB - Springer Nature
SP - 3305-3315
IS - 11
VL - 24
SN - 0947-7047
SN - 1862-0760
ER -
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@article{2018_Li,
author = {Yuan Li and Tiantian Yang and Weiwei Wu and Zhenzhu Cao and Weiyan He and Yanfang Gao and Jinrong Liu and Guorong Li},
title = {Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics},
journal = {Ionics},
year = {2018},
volume = {24},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11581-018-2497-3},
number = {11},
pages = {3305--3315},
doi = {10.1007/s11581-018-2497-3}
}
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MLA
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Li, Yuan, et al. “Effect of Al-Mo codoping on the structure and ionic conductivity of sol-gel derived Li7La3Zr2O12 ceramics.” Ionics, vol. 24, no. 11, Mar. 2018, pp. 3305-3315. https://doi.org/10.1007/s11581-018-2497-3.