Ionics, volume 25, issue 10, pages 4713-4725
Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties
Publication type: Journal Article
Publication date: 2019-05-17
General Chemical Engineering
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
High-conductivity NASICON-type solid electrolytes of Li1.5Al0.5Ge1.5(PO4)3 composition have been obtained through glass crystallization. Thermal behavior of the precursor glass has been investigated; glass transition and crystallization temperatures have been determined by DSC. The influence of glass crystallization temperature (750, 800, 820, and 850 °C) on the phase composition, microstructure, molecular structure, and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 glass-ceramics has been studied. It was found that the optimum crystallization temperature for obtaining an electrolyte with the highest conductivity (0.39 mS cm−1 at 25 °C) is 820 °C.
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Citations by publishers
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- We do not take into account publications without a DOI.
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Pershina S. V. et al. Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties // Ionics. 2019. Vol. 25. No. 10. pp. 4713-4725.
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Pershina S. V., Pankratov A. A., Vovkotrub E. G., Antonov B. D. Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties // Ionics. 2019. Vol. 25. No. 10. pp. 4713-4725.
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TY - JOUR
DO - 10.1007/s11581-019-03021-5
UR - http://link.springer.com/10.1007/s11581-019-03021-5
TI - Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties
T2 - Ionics
AU - Pershina, S V
AU - Pankratov, A. A.
AU - Vovkotrub, E. G.
AU - Antonov, B. D.
PY - 2019
DA - 2019/05/17 00:00:00
PB - Springer Nature
SP - 4713-4725
IS - 10
VL - 25
SN - 0947-7047
SN - 1862-0760
ER -
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@article{2019_Pershina,
author = {S V Pershina and A. A. Pankratov and E. G. Vovkotrub and B. D. Antonov},
title = {Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties},
journal = {Ionics},
year = {2019},
volume = {25},
publisher = {Springer Nature},
month = {may},
url = {http://link.springer.com/10.1007/s11581-019-03021-5},
number = {10},
pages = {4713--4725},
doi = {10.1007/s11581-019-03021-5}
}
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MLA
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Pershina, S. V., et al. “Promising high-conductivity Li1.5Al0.5Ge1.5(PO4)3 solid electrolytes: the effect of crystallization temperature on the microstructure and transport properties.” Ionics, vol. 25, no. 10, May. 2019, pp. 4713-4725. http://link.springer.com/10.1007/s11581-019-03021-5.