Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation
Publication type: Journal Article
Publication date: 2022-06-17
scimago Q2
wos Q3
SJR: 0.532
CiteScore: 4.5
Impact factor: 2.6
ISSN: 09477047, 18620760
General Chemical Engineering
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
Cathode modification by Li2O–B2O3–SiO2 glass addition can be considered one of the ways to solve the problem of the increased interfacial resistance between solid electrolyte and solid cathode. The chemical and thermal stability of composite solid electrolyte based on Li7La3Zr2O12 in contact with LiCoO2 and glass additive was studied using XRD and DSC analysis. It was established that the interaction in the mixture studied begins at 670 °C. Therefore, 650 °C at 1 h was chosen as heat treatment conditions for (100-x)LiCoO2 + x 65Li2O·27B2O3·8SiO2 | solid electrolyte half-cells (x = 0–20 wt%). It was established that 5 wt% of glass addition is optimal to reduce the interfacial resistance. It can be concluded that Li2O–B2O3–SiO2 glass addition in LiCoO2 leads to the tight contact with composite electrolyte based on Li7La3Zr2O12 and the decrease in the interface resistance between the two solids.
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Ilina E. A. et al. Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation // Ionics. 2022. Vol. 28. No. 8. pp. 3635-3642.
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Ilina E. A., Lyalin E. D., Kuznetsova T. A., Pankratov A. A. Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation // Ionics. 2022. Vol. 28. No. 8. pp. 3635-3642.
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TY - JOUR
DO - 10.1007/s11581-022-04640-1
UR - https://doi.org/10.1007/s11581-022-04640-1
TI - Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation
T2 - Ionics
AU - Ilina, E A
AU - Lyalin, E D
AU - Kuznetsova, T. A.
AU - Pankratov, A. A.
PY - 2022
DA - 2022/06/17
PB - Springer Nature
SP - 3635-3642
IS - 8
VL - 28
SN - 0947-7047
SN - 1862-0760
ER -
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BibTex (up to 50 authors)
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@article{2022_Ilina,
author = {E A Ilina and E D Lyalin and T. A. Kuznetsova and A. A. Pankratov},
title = {Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation},
journal = {Ionics},
year = {2022},
volume = {28},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11581-022-04640-1},
number = {8},
pages = {3635--3642},
doi = {10.1007/s11581-022-04640-1}
}
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MLA
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Ilina, E. A., et al. “Cathode modification by Li2O–B2O3–SiO2 glass addition for all-solid-state battery creation.” Ionics, vol. 28, no. 8, Jun. 2022, pp. 3635-3642. https://doi.org/10.1007/s11581-022-04640-1.
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