volume 45 issue 3 pages 1705-1710

Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO

A.I. Voronin 1
A A Usenko 1
V V Khovaylo 3
L V Shvanskaya 1, 4
A. T. BURKOV 3, 5
A. N. Vasiliev 1, 6
Publication typeJournal Article
Publication date2015-11-13
scimago Q2
wos Q2
SJR0.475
CiteScore4.3
Impact factor2.5
ISSN03615235, 1543186X
Materials Chemistry
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Abstract
We examined the effect of NaF doping on the thermoelectric properties of p-type Bi1−x Na x CuSeO1−x F x (x = 0, 0.05, 0.10, 0.15) synthesized by a facile method combining a solid-state reaction and spark plasma sintering. The substitution of Bi3+ by Na+ and O2− by F− led to an enhancement of electrical conductivity and a slight increase in thermal conductivity, while the Seebeck coefficient was slightly affected by the doping. The power factor (2.12 μW cm−1 K−2 at 923 K) and the low thermal conductivity resulted in the dimensionless figure␣of merit ZT 0.42 for Bi0.95Na0.05CuSeO0.95F0.05 at 923 K. The obtained results indicated that ZT was not improved by the double substitution at the bismuth and oxygen sites.
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Novitskii A. et al. Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO // Journal of Electronic Materials. 2015. Vol. 45. No. 3. pp. 1705-1710.
GOST all authors (up to 50) Copy
Novitskii A., Voronin A., Usenko A. A., Gorshenkov M. V., Khovaylo V. V., Shvanskaya L. V., BURKOV A. T., Vasiliev A. N. Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO // Journal of Electronic Materials. 2015. Vol. 45. No. 3. pp. 1705-1710.
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RIS Copy
TY - JOUR
DO - 10.1007/s11664-015-4181-y
UR - http://link.springer.com/10.1007/s11664-015-4181-y
TI - Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO
T2 - Journal of Electronic Materials
AU - Novitskii, Andrei
AU - Voronin, A.I.
AU - Usenko, A A
AU - Gorshenkov, M V
AU - Khovaylo, V V
AU - Shvanskaya, L V
AU - BURKOV, A. T.
AU - Vasiliev, A. N.
PY - 2015
DA - 2015/11/13
PB - Springer Nature
SP - 1705-1710
IS - 3
VL - 45
SN - 0361-5235
SN - 1543-186X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Novitskii,
author = {Andrei Novitskii and A.I. Voronin and A A Usenko and M V Gorshenkov and V V Khovaylo and L V Shvanskaya and A. T. BURKOV and A. N. Vasiliev},
title = {Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO},
journal = {Journal of Electronic Materials},
year = {2015},
volume = {45},
publisher = {Springer Nature},
month = {nov},
url = {http://link.springer.com/10.1007/s11664-015-4181-y},
number = {3},
pages = {1705--1710},
doi = {10.1007/s11664-015-4181-y}
}
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Novitskii, Andrei, et al. “Influence of Sodium Fluoride Doping on Thermoelectric Properties of BiCuSeO.” Journal of Electronic Materials, vol. 45, no. 3, Nov. 2015, pp. 1705-1710. http://link.springer.com/10.1007/s11664-015-4181-y.