Journal of Electronic Materials, volume 49, issue 8, pages 4910-4915
Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation
Tuo Wang
1, 2
,
Xin Zhang
1, 2
,
Zhongran Yao
1, 2
,
Jun Li
1, 2
,
Kongjun Zhu
1
,
Jing Wang
1
,
Kang Yan
1
Publication type: Journal Article
Publication date: 2020-05-26
Journal:
Journal of Electronic Materials
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 03615235, 1543186X
Materials Chemistry
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Abstract
Garnet-like solid electrolyte ceramics, Li7La3Zr2−xTixO12 (LLZTO, x = 0, 0.1, 0.2, and 0.3), were successfully synthesized at low temperature via chemical co-precipitation. The composition and phase transformation during the heating of the LLZTO precursors are analyzed using thermal gravimetric and differential thermal analysis and x-ray diffraction. The results indicated that 900°C was the likely activation point of LLZTO precursor powder crystallization and all the samples sintered at 1120°C formed a single phase with cubic garnet-like structure. The different morphologies of the LLZTO are characterized using scanning electron microscopy. As the content of Ti increased, the grain size increased to 20 μm, and few pores are observed on the grain boundaries. Additionally, Ti doping increased the ionic conductivity of LLZO ceramics: the sample with x = 0.1 reaches a maximum total ionic conductivity of 1.91 × 10−4 S cm−1 at 298 K and its activation energy is 0.33 eV, which may be a significant step towards the goal of an ultimate safe solid electrolyte of a solid-state lithium ion battery.
Top-30
Citations by journals
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2
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Small
2 publications, 14.29%
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Journal of the Electrochemical Society
1 publication, 7.14%
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Journal of Materials Science: Materials in Electronics
1 publication, 7.14%
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Ionics
1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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Journal of Energy Storage
1 publication, 7.14%
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Journal of Solid State Electrochemistry
1 publication, 7.14%
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Ceramics International
1 publication, 7.14%
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International Journal of Molecular Sciences
1 publication, 7.14%
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Journal of Materials Science
1 publication, 7.14%
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Advanced Energy Materials
1 publication, 7.14%
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Russian Chemical Reviews
1 publication, 7.14%
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2
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Citations by publishers
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4
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Springer Nature
4 publications, 28.57%
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Elsevier
3 publications, 21.43%
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Wiley
3 publications, 21.43%
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The Electrochemical Society
1 publication, 7.14%
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American Chemical Society (ACS)
1 publication, 7.14%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 7.14%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.14%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Wang T. et al. Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation // Journal of Electronic Materials. 2020. Vol. 49. No. 8. pp. 4910-4915.
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Wang T., Zhang X., Yao Z., Li J., Zhu K., Wang J., Yan K. Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation // Journal of Electronic Materials. 2020. Vol. 49. No. 8. pp. 4910-4915.
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TY - JOUR
DO - 10.1007/s11664-020-08221-8
UR - https://doi.org/10.1007/s11664-020-08221-8
TI - Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation
T2 - Journal of Electronic Materials
AU - Wang, Tuo
AU - Zhang, Xin
AU - Yao, Zhongran
AU - Li, Jun
AU - Zhu, Kongjun
AU - Wang, Jing
AU - Yan, Kang
PY - 2020
DA - 2020/05/26 00:00:00
PB - Springer Nature
SP - 4910-4915
IS - 8
VL - 49
SN - 0361-5235
SN - 1543-186X
ER -
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@article{2020_Wang,
author = {Tuo Wang and Xin Zhang and Zhongran Yao and Jun Li and Kongjun Zhu and Jing Wang and Kang Yan},
title = {Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation},
journal = {Journal of Electronic Materials},
year = {2020},
volume = {49},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s11664-020-08221-8},
number = {8},
pages = {4910--4915},
doi = {10.1007/s11664-020-08221-8}
}
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Wang, Tuo, et al. “Processing and Enhanced Electrochemical Properties of Li7La3Zr2−xTixO12 Solid Electrolyte by Chemical Co-precipitation.” Journal of Electronic Materials, vol. 49, no. 8, May. 2020, pp. 4910-4915. https://doi.org/10.1007/s11664-020-08221-8.