Korean Journal of Chemical Engineering, volume 33, issue 1, pages 305-311

A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications

Publication typeJournal Article
Publication date2015-09-17
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor2.7
ISSN02561115, 19757220
General Chemistry
General Chemical Engineering
Abstract
A simple method to synthesize silver selenide nanoparticles has been proposed. By changing the ratio of Se-oleylamine complex and silver acetate in the reacting mixture at different temperatures, both size and stoichiometry of the silver selenide particles could be successfully controlled. The size of the nanoparticles was adjusted by changing reaction temperatures. The synthesized silver selenide nanoparticles showed size changes from 3 to 10 nm when the corresponding reaction temperatures were 40–100°C, respectively. In addition to the size change, the stoichiometry of the synthesized nanoparticles (Ag2+x Se) could be adjusted by simply varying the ratio of Ag to Se precursors. Through XPS analyses the x value in Ag2+x Se was determined, and it changed between 0.54 and −0.03 by varying Ag/Se ratio from 2/0.75 to 2/4. The optical property of the nonstoichiometric Ag2+x Se nanoparticles was different from that of stoichiometric Ag2Se nanoparticles, but showed the plasmon absorption of Ag-Ag network. The plasmon absorption was decreased with the increased concentration of the Se precursor. Finally, the Ag2+x Se thin film in this work showed large magnetoresistance and successfully applied to prepare high-performance Schottky diode. The Ag2.06Se film exhibited the magnetoresistance effect up to 0.9% at only 0.8 T at room temperature. The voltage drop and breakdown voltage of the Schottky diode were 0.5 V and 9.3 V, respectively.

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GOST Copy
Vo D. Q. et al. A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications // Korean Journal of Chemical Engineering. 2015. Vol. 33. No. 1. pp. 305-311.
GOST all authors (up to 50) Copy
Vo D. Q., Dung D. D., Cho S., Kim S. A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications // Korean Journal of Chemical Engineering. 2015. Vol. 33. No. 1. pp. 305-311.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11814-015-0141-8
UR - https://doi.org/10.1007/s11814-015-0141-8
TI - A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications
T2 - Korean Journal of Chemical Engineering
AU - Vo, Duc Quy
AU - Dung, Dang Duc
AU - Cho, Sunglae
AU - Kim, Sunwook
PY - 2015
DA - 2015/09/17 00:00:00
PB - Springer Nature
SP - 305-311
IS - 1
VL - 33
SN - 0256-1115
SN - 1975-7220
ER -
BibTex |
Cite this
BibTex Copy
@article{2015_Vo,
author = {Duc Quy Vo and Dang Duc Dung and Sunglae Cho and Sunwook Kim},
title = {A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications},
journal = {Korean Journal of Chemical Engineering},
year = {2015},
volume = {33},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s11814-015-0141-8},
number = {1},
pages = {305--311},
doi = {10.1007/s11814-015-0141-8}
}
MLA
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MLA Copy
Vo, Duc Quy, et al. “A simple synthesis of Ag2+x Se nanoparticles and their thin films for electronic device applications.” Korean Journal of Chemical Engineering, vol. 33, no. 1, Sep. 2015, pp. 305-311. https://doi.org/10.1007/s11814-015-0141-8.
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