Journal of Chemical Sciences, volume 136, issue 1, publication number 5
KOH-catalyzed cross-coupling of primary and secondary alcohols: evidence for radical pathways
Publication type: Journal Article
Publication date: 2024-01-18
Journal:
Journal of Chemical Sciences
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.7
ISSN: 09743626, 09737103, 02534134
General Chemistry
Abstract
A simple base, KOH-catalyzed cross-coupling of primary and secondary alcohols is reported in which the primary alcohols play the role of alkylation reagents. EPR and mechanistic studies confirmed the involvement of radical and ketone intermediates formed from primary and secondary alcohols, respectively, leading to the formation of β-alkylated secondary alcohols. A simple base-catalyzed synthesis of higher secondary alcohols directly from the cross-coupling of primary and secondary alcohols is reported.
Top-30
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Russian Chemical Reviews
1 publication, 100%
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Citations by publishers
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 100%
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Nayak A. S. et al. KOH-catalyzed cross-coupling of primary and secondary alcohols: evidence for radical pathways // Journal of Chemical Sciences. 2024. Vol. 136. No. 1. 5
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Nayak A. S., Jaiswal S., Sahu M. K., Gunanathan C. KOH-catalyzed cross-coupling of primary and secondary alcohols: evidence for radical pathways // Journal of Chemical Sciences. 2024. Vol. 136. No. 1. 5
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TY - JOUR
DO - 10.1007/s12039-023-02241-7
UR - https://doi.org/10.1007/s12039-023-02241-7
TI - KOH-catalyzed cross-coupling of primary and secondary alcohols: evidence for radical pathways
T2 - Journal of Chemical Sciences
AU - Nayak, Amlan Subhadarshi
AU - Jaiswal, Shubham
AU - Sahu, Manas Kumar
AU - Gunanathan, Chidambaram
PY - 2024
DA - 2024/01/18 00:00:00
PB - Springer Nature
IS - 1
VL - 136
SN - 0974-3626
SN - 0973-7103
SN - 0253-4134
ER -
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@article{2024_Nayak,
author = {Amlan Subhadarshi Nayak and Shubham Jaiswal and Manas Kumar Sahu and Chidambaram Gunanathan},
title = {KOH-catalyzed cross-coupling of primary and secondary alcohols: evidence for radical pathways},
journal = {Journal of Chemical Sciences},
year = {2024},
volume = {136},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s12039-023-02241-7},
number = {1},
doi = {10.1007/s12039-023-02241-7}
}
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