Applied Nanoscience (Switzerland), volume 10, issue 4, pages 1023-1033
Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications
Isachenko Andrey I
1
,
Apyari Vladimir
1
,
Melekhin Artem O
1
,
Garshev Alexey V.
1, 2
,
Volkov Pavel A.
3
,
Publication type: Journal Article
Publication date: 2020-02-28
Journal:
Applied Nanoscience (Switzerland)
Quartile SCImago
Q2
Quartile WOS
—
Impact factor: —
ISSN: 21905509, 21905517
Physical and Theoretical Chemistry
Cell Biology
Biotechnology
Atomic and Molecular Physics, and Optics
Materials Science (miscellaneous)
Electrical and Electronic Engineering
Abstract
Currently a lot of synthetic routs have been proposed for preparation of various metal nanoparticles for sensing applications. A majority of them are based on the borohydride approach. We have found that some polymers (e.g. polyurethane) can be a promising support for immobilization of borohydride. The present work describes a method for preparation of polyurethane foam modified with borohydride as a new form of the widely known reducing agent and its possibilities for synthesis of metal nanoparticles. This new reagent is quite stable when stored at low temperature and is convenient for use in the synthesis of nanoparticles since it ensures precise dosing of a reductant. Metal nanoparticles could be synthesized both in solution and on polymer surface by varying reagents concentrations during the modified polyurethane foam preparation. It was illustrated that nanoparticles prepared using the borohydride-modified polymer have a narrower size distribution that probably should be ascribed to the stabilizing effect of the polymeric matrix. Optical properties of polyurethane foam-based nanocomposites with metal nanoparticles open a possibility of their using for sensing substances that affect formation of nanoparticles or their distribution between the polymer and the solution.
Citations by journals
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1
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Talanta
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Talanta
1 publication, 25%
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IEEE Transactions on Instrumentation and Measurement
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IEEE Transactions on Instrumentation and Measurement
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The Analyst
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The Analyst
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Polymer Science - Series A
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1 publication, 25%
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1
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Citations by publishers
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1
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Elsevier
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Elsevier
1 publication, 25%
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IEEE
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IEEE
1 publication, 25%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 25%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 25%
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1
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Isachenko A. I. et al. Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications // Applied Nanoscience (Switzerland). 2020. Vol. 10. No. 4. pp. 1023-1033.
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Isachenko A. I., Apyari V., Melekhin A. O., Garshev A. V., Volkov P. A., Dmitrienko S. G. Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications // Applied Nanoscience (Switzerland). 2020. Vol. 10. No. 4. pp. 1023-1033.
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TY - JOUR
DO - 10.1007/s13204-020-01281-6
UR - https://doi.org/10.1007%2Fs13204-020-01281-6
TI - Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications
T2 - Applied Nanoscience (Switzerland)
AU - Isachenko, Andrey I
AU - Apyari, Vladimir
AU - Melekhin, Artem O
AU - Garshev, Alexey V.
AU - Volkov, Pavel A.
AU - Dmitrienko, Stanislava G
PY - 2020
DA - 2020/02/28 00:00:00
PB - Springer Nature
SP - 1023-1033
IS - 4
VL - 10
SN - 2190-5509
SN - 2190-5517
ER -
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@article{2020_Isachenko,
author = {Andrey I Isachenko and Vladimir Apyari and Artem O Melekhin and Alexey V. Garshev and Pavel A. Volkov and Stanislava G Dmitrienko},
title = {Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications},
journal = {Applied Nanoscience (Switzerland)},
year = {2020},
volume = {10},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007%2Fs13204-020-01281-6},
number = {4},
pages = {1023--1033},
doi = {10.1007/s13204-020-01281-6}
}
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MLA
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Isachenko, Andrey I., et al. “Borohydride-modified polyurethane foam: a new form of a widely known reducing agent in synthesis of metal nanoparticles for sensing applications.” Applied Nanoscience (Switzerland), vol. 10, no. 4, Feb. 2020, pp. 1023-1033. https://doi.org/10.1007%2Fs13204-020-01281-6.