European Polymer Journal, volume 28, issue 5, pages 555-559
Organotin polymers—XVI. Synthesis of p-acryloyloxybenzoic acid and n-methacryloyloxytetrabromophthalimide and copolymerizations with tri-n-butyltin acrylate and methacrylate
A. A. MAHMOUD
1
,
A.F. Shaaban
1
,
Mohamed Azab
1
,
N.N. Messiha
2
2
Laboratory of Polymers and Pigments, National Research Center, Dokki, Cairo, Egypt
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Publication type: Journal Article
Publication date: 1992-05-01
Journal:
European Polymer Journal
scimago Q1
wos Q1
SJR: 0.982
CiteScore: 9.9
Impact factor: 5.8
ISSN: 00143057, 18731945
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Abstract
p -Acryloyloxybenzoic acid (ABA) and N -methacryloyloxytetrabromophthalimide (NMTP) were prepared. The monomer reactivity ratios for the copolymerization of tri-n-butyltin acrylate (monomer-1) with ABA and NMTP have been found to be r 1 , = 1.01, r 2 = 0.40 and r 1 , = 0.69, r 2 = 0.90 respectively; those for tri-n-butyltin methacrylate (monomer-l) with ABA and NMTP were r 1 = 2.21, r 2 = 0.87 and r 1 = 0.85, r 2 = 1.35 respectively. Copolymerizations were carried out in solution at 70° using 1 mol% azobisisobutyronitrile as initiator. The structures of the monomers were investigated by i.r. and 1 H-NMR.
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