An evaluation of the rotational barrier about the BN bond of 1-aminoborepins
Publication type: Journal Article
Publication date: 1994-04-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
13C NMR spectroscopy has been used to determined the barriers to rotation about the BN bonds of 1-(N-benzyl-N-methylamino)borepin and 1-(N-benzyl-N-methylamino)-4,5-dihydroborepin as 18 and 19.8 kcal mol−1, respectively. The corresponding rotational barriers of a variety of aminoboranes have been calculated using the semi-empirical AM1 method.
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Ashe A. J. et al. An evaluation of the rotational barrier about the BN bond of 1-aminoborepins // Journal of Organometallic Chemistry. 1994. Vol. 468. No. 1-2. pp. 21-23.
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Ashe A. J., Klein W., Rousseau R. An evaluation of the rotational barrier about the BN bond of 1-aminoborepins // Journal of Organometallic Chemistry. 1994. Vol. 468. No. 1-2. pp. 21-23.
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TY - JOUR
DO - 10.1016/0022-328X(94)80025-1
UR - https://doi.org/10.1016/0022-328X(94)80025-1
TI - An evaluation of the rotational barrier about the BN bond of 1-aminoborepins
T2 - Journal of Organometallic Chemistry
AU - Ashe, Arthur J
AU - Klein, Wolfram
AU - Rousseau, Roger
PY - 1994
DA - 1994/04/01
PB - Elsevier
SP - 21-23
IS - 1-2
VL - 468
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1994_Ashe,
author = {Arthur J Ashe and Wolfram Klein and Roger Rousseau},
title = {An evaluation of the rotational barrier about the BN bond of 1-aminoborepins},
journal = {Journal of Organometallic Chemistry},
year = {1994},
volume = {468},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0022-328X(94)80025-1},
number = {1-2},
pages = {21--23},
doi = {10.1016/0022-328X(94)80025-1}
}
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MLA
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Ashe, Arthur J., et al. “An evaluation of the rotational barrier about the BN bond of 1-aminoborepins.” Journal of Organometallic Chemistry, vol. 468, no. 1-2, Apr. 1994, pp. 21-23. https://doi.org/10.1016/0022-328X(94)80025-1.