The structure and properties of Li1−xHxNbO3
1
AT&T Bell Labs Murray Hill, New Jersey 07974, USA
|
Publication type: Journal Article
Publication date: 1986-09-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
The properties of Li 1− x H x NbO 3 have been studied as a function of x , temperature, and stoichiometry of the LiNbO 3 used for its preparation. X-ray diffraction, thermal analysis measurements, and infrared spectroscopy have been used. The intent of this study was to gain a deeper understanding of the basic properties of this material, which has potential importance as a waveguide material in LiNbO 3 optical devices. An approximate phase diagram was constructed for the stoichiometric LiNbO 3 HNbO 3 system. In one concentration range (0.56 ≤ x ≤ 0.75), particularly complex structural behavior was found: depending on x , samples undergo one, two, or three phase transitions with temperature, and the system appears to exhibit critical behavior. Samples made by proton exchange of congruent LiNbO 3 ([Li 2 O] 0.486 [Nb 2 O 5 ] 0.514 ) show generally similar structural chemistry, with one exception: a new monoclinic phase, isomorphous with MnF 3 , was found for 0.75 ≤ x ≤ 0.77. Possible reasons for the refractive index changes caused by proton exchange are discussed.
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Total citations:
122
Citations from 2024:
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(1.64%)
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GOST
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Rice C. E. The structure and properties of Li1−xHxNbO3 // Journal of Solid State Chemistry. 1986. Vol. 64. No. 2. pp. 188-199.
GOST all authors (up to 50)
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Rice C. E. The structure and properties of Li1−xHxNbO3 // Journal of Solid State Chemistry. 1986. Vol. 64. No. 2. pp. 188-199.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0022-4596(86)90138-6
UR - https://doi.org/10.1016/0022-4596(86)90138-6
TI - The structure and properties of Li1−xHxNbO3
T2 - Journal of Solid State Chemistry
AU - Rice, C. E.
PY - 1986
DA - 1986/09/01
PB - Elsevier
SP - 188-199
IS - 2
VL - 64
SN - 0022-4596
SN - 1095-726X
ER -
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BibTex (up to 50 authors)
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@article{1986_Rice,
author = {C. E. Rice},
title = {The structure and properties of Li1−xHxNbO3},
journal = {Journal of Solid State Chemistry},
year = {1986},
volume = {64},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/0022-4596(86)90138-6},
number = {2},
pages = {188--199},
doi = {10.1016/0022-4596(86)90138-6}
}
Cite this
MLA
Copy
Rice, C. E.. “The structure and properties of Li1−xHxNbO3.” Journal of Solid State Chemistry, vol. 64, no. 2, Sep. 1986, pp. 188-199. https://doi.org/10.1016/0022-4596(86)90138-6.