Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2
Publication type: Journal Article
Publication date: 1972-05-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
The interdiffusion of Cr2O3 and TiO2 has been studied between 990 and 1520°C in the range of concentrations for which the solid phase is a rutile solid solution. The concentration limits of this phase have been determined. At low concentrations the interdiffusion coefficient varies approximately as chromium concentration but decreases again at higher concentration. The ratio of the diffusion coefficients parallel and perpendicular to the rutile c-axis decreases from 4.0 at 990°C to 1.75 at 1520°C. Attention is drawn to some features of the problem of evaluation of interdiffusion coefficients in systems of variable molar volume.
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Total citations:
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GOST
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O'Keeffe M., Ribble T. J. Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2 // Journal of Solid State Chemistry. 1972. Vol. 4. No. 3. pp. 351-356.
GOST all authors (up to 50)
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O'Keeffe M., Ribble T. J. Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2 // Journal of Solid State Chemistry. 1972. Vol. 4. No. 3. pp. 351-356.
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RIS
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TY - JOUR
DO - 10.1016/0022-4596(72)90148-x
UR - https://doi.org/10.1016/0022-4596(72)90148-x
TI - Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2
T2 - Journal of Solid State Chemistry
AU - O'Keeffe, M.
AU - Ribble, T J
PY - 1972
DA - 1972/05/01
PB - Elsevier
SP - 351-356
IS - 3
VL - 4
SN - 0022-4596
SN - 1095-726X
ER -
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BibTex (up to 50 authors)
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@article{1972_O'Keeffe,
author = {M. O'Keeffe and T J Ribble},
title = {Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2},
journal = {Journal of Solid State Chemistry},
year = {1972},
volume = {4},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0022-4596(72)90148-x},
number = {3},
pages = {351--356},
doi = {10.1016/0022-4596(72)90148-x}
}
Cite this
MLA
Copy
O'Keeffe, M., and T J Ribble. “Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2.” Journal of Solid State Chemistry, vol. 4, no. 3, May. 1972, pp. 351-356. https://doi.org/10.1016/0022-4596(72)90148-x.