Journal of Solid State Chemistry

, том 4 , издание 3 , страницы 351-356

Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2

Тип публикации: Journal Article

Дата публикации: 1972-05-01

Elsevier

Journal of Solid State Chemistry

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white level БС2

SJR: 0.629

CiteScore: 6.8

Impact factor: 3.5

ISSN: 00224596, 1095726X

DOI: 10.1016/0022-4596(72)90148-x

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Materials Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Inorganic Chemistry

Physical and Theoretical Chemistry

Condensed Matter Physics

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The interdiffusion of Cr2O3 and TiO2 has been studied between 990 and 1520°C in the range of concentrations for which the solid phase is a rutile solid solution. The concentration limits of this phase have been determined. At low concentrations the interdiffusion coefficient varies approximately as chromium concentration but decreases again at higher concentration. The ratio of the diffusion coefficients parallel and perpendicular to the rutile c-axis decreases from 4.0 at 990°C to 1.75 at 1520°C. Attention is drawn to some features of the problem of evaluation of interdiffusion coefficients in systems of variable molar volume.

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O'Keeffe M., Ribble T. J. Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2 // Journal of Solid State Chemistry. 1972. Vol. 4. No. 3. pp. 351-356.

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O'Keeffe M., Ribble T. J. Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2 // Journal of Solid State Chemistry. 1972. Vol. 4. No. 3. pp. 351-356.

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TY - JOUR

DO - 10.1016/0022-4596(72)90148-x

UR - https://doi.org/10.1016/0022-4596(72)90148-x

TI - Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2

T2 - Journal of Solid State Chemistry

AU - O'Keeffe, M.

AU - Ribble, T J

PY - 1972

DA - 1972/05/01

PB - Elsevier

SP - 351-356

IS - 3

VL - 4

SN - 0022-4596

SN - 1095-726X

ER -

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@article{1972_O'Keeffe,

author = {M. O'Keeffe and T J Ribble},

title = {Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2},

journal = {Journal of Solid State Chemistry},

year = {1972},

volume = {4},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/0022-4596(72)90148-x},

number = {3},

pages = {351--356},

doi = {10.1016/0022-4596(72)90148-x}

}

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O'Keeffe, M., and T J Ribble. “Interdiffusion and the solubility limits of Cr2O3 in the rutile phase of TiO2.” Journal of Solid State Chemistry, vol. 4, no. 3, May. 1972, pp. 351-356. https://doi.org/10.1016/0022-4596(72)90148-x.