ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses
Publication type: Journal Article
Publication date: 1985-03-01
scimago Q2
wos Q3
SJR: 0.446
CiteScore: 4.3
Impact factor: 2.4
ISSN: 00381098, 18792766
Materials Chemistry
General Chemistry
Condensed Matter Physics
Abstract
A correlated ESR and Mossbauer spectroscopic study of the glass system 2CaO3B2O3.Al2O3.xFe2O3 (0.1⩽x⩽1) is reported. At low Fe contents (x⩽0.1) Fe3+ ions are found only in tetrahedral environments, giving a single, sharp ESR peak at g=4.13. For higher x, occupation by Fe3+ of other-symmetry sites become possible, as seen by the evolution of g=2.0 and g=6.0 ESR features. A careful examination of Mossbauer isomer shift data has yielded an average value of 1.96 A for the Fe3+−O2− distance, besides confirming the tetrahedral site symmetry. Using this value, and quadrupole splitting data the extent of angular distortion (α) from perfect tetrahedral symmetry has been deduced as 30° from a calculation based on Newman's superposition model.
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SUNANDANA C. S., Jagannathan R. ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses // Solid State Communications. 1985. Vol. 53. No. 11. pp. 985-988.
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SUNANDANA C. S., Jagannathan R. ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses // Solid State Communications. 1985. Vol. 53. No. 11. pp. 985-988.
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TY - JOUR
DO - 10.1016/0038-1098(85)90474-0
UR - https://doi.org/10.1016/0038-1098(85)90474-0
TI - ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses
T2 - Solid State Communications
AU - SUNANDANA, C. S.
AU - Jagannathan, R.
PY - 1985
DA - 1985/03/01
PB - Elsevier
SP - 985-988
IS - 11
VL - 53
SN - 0038-1098
SN - 1879-2766
ER -
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BibTex (up to 50 authors)
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@article{1985_SUNANDANA,
author = {C. S. SUNANDANA and R. Jagannathan},
title = {ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses},
journal = {Solid State Communications},
year = {1985},
volume = {53},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/0038-1098(85)90474-0},
number = {11},
pages = {985--988},
doi = {10.1016/0038-1098(85)90474-0}
}
Cite this
MLA
Copy
SUNANDANA, C. S., and R. Jagannathan. “ESR and Mössbauer studies of Fe3+ ion in calcium boro-aluminate glasses.” Solid State Communications, vol. 53, no. 11, Mar. 1985, pp. 985-988. https://doi.org/10.1016/0038-1098(85)90474-0.