Biosynthesis of isotetrandrine
Publication type: Journal Article
Publication date: 1980-01-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The incorporation of (±)-coclaurine, (±)-N-methylcoclaurine, didehydro-N-methylcoclaurinium iodide, (+)-( S )-N-methylcoclaurine and (−)-( R )-N-methylcoclaurine into isotetrandrine in Cocculus laurifolius DC has been studied and specific utilization of (±)-, (+)-( S )- and (−)- R -N-methylcoclaurines and didehydro-N-methylcoclaurinium iodide demonstrated. The evidence supports intermolecular oxidative coupline of (+)-( S )- and (−)-( R )-N-methylcoclaurines to form isotetrandrine. Double labelling experiment with (±)-N- [ 14 C] methyl [1 - 3 H] coclaurine demonstrated that the hydrogen atom at the asymmetric centre in N-methylcoclaurine is retained in the bioconversion into isotetrandrine.
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Total citations:
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RIS
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TY - JOUR
DO - 10.1016/0040-4020(80)80107-4
UR - https://doi.org/10.1016/0040-4020(80)80107-4
TI - Biosynthesis of isotetrandrine
T2 - Tetrahedron
AU - Bhakuni, Dewan S
AU - Singh, Awadhesh Kumar
AU - Jain, Sudha
PY - 1980
DA - 1980/01/01
PB - Elsevier
SP - 2149-2151
IS - 14
VL - 36
SN - 0040-4020
SN - 1464-5416
ER -
Cite this
BibTex (up to 50 authors)
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@article{1980_Bhakuni,
author = {Dewan S Bhakuni and Awadhesh Kumar Singh and Sudha Jain},
title = {Biosynthesis of isotetrandrine},
journal = {Tetrahedron},
year = {1980},
volume = {36},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0040-4020(80)80107-4},
number = {14},
pages = {2149--2151},
doi = {10.1016/0040-4020(80)80107-4}
}
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MLA
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Bhakuni, Dewan S., et al. “Biosynthesis of isotetrandrine.” Tetrahedron, vol. 36, no. 14, Jan. 1980, pp. 2149-2151. https://doi.org/10.1016/0040-4020(80)80107-4.