Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles
Publication type: Journal Article
Publication date: 1995-02-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The reaction of C60 to acylnitrenes 2, generated by photolysis of aroylazides 1 in dichloromethane, creates the stable fulleroaziridine derivatives 3a, 3b, 3c and 3d. The rearrangement of the fulleroaziridines 3 by boiling in tetrachloroethane leads to the formation of the corresponding fullerooxazoles 4a, 4b, 4c, and 4d. The formation of a fullerooxazole 4b was also observed by irradiation of C60 and 1b in benzene.
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Total citations:
45
Citations from 2025:
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(2.22%)
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GOST
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Averdung J. et al. Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles // Tetrahedron. 1995. Vol. 51. No. 9. pp. 2543-2552.
GOST all authors (up to 50)
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Averdung J., Mattay J., Jacobi D., Werner A. Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles // Tetrahedron. 1995. Vol. 51. No. 9. pp. 2543-2552.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0040-4020(95)00013-X
UR - https://doi.org/10.1016/0040-4020(95)00013-X
TI - Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles
T2 - Tetrahedron
AU - Averdung, Johannes
AU - Mattay, Jochen
AU - Jacobi, Dirk
AU - Werner, Abraham
PY - 1995
DA - 1995/02/01
PB - Elsevier
SP - 2543-2552
IS - 9
VL - 51
SN - 0040-4020
SN - 1464-5416
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1995_Averdung,
author = {Johannes Averdung and Jochen Mattay and Dirk Jacobi and Abraham Werner},
title = {Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles},
journal = {Tetrahedron},
year = {1995},
volume = {51},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/0040-4020(95)00013-X},
number = {9},
pages = {2543--2552},
doi = {10.1016/0040-4020(95)00013-X}
}
Cite this
MLA
Copy
Averdung, Johannes, et al. “Addition of photochemically generated acylnitrenes to C60. Synthesis of fulleroaziridines and thermal rearrangement to fullerooxazoles.” Tetrahedron, vol. 51, no. 9, Feb. 1995, pp. 2543-2552. https://doi.org/10.1016/0040-4020(95)00013-X.