Thermochimica Acta, volume 200, pages 427-441
The thermal decomposition of tetrazoles
Publication type: Journal Article
Publication date: 1992-07-01
Journal:
Thermochimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.5
ISSN: 00406031, 1872762X
Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation
Abstract
A brief review of the literature on the thermal decomposition of chemical compounds containing a tetrazole heterocycle is given. It is shown that there are two radically different pathways of the tetrazole cycle fragmentation connected with the formation of a molecule of nitrogen or azides. The elimination of nitrogen from 2,5-disubstituted tetrazoles results in a nitrilimine. The elimination of nitrogen from 1,5-disubstituted tetrazoles leads to the formation of a nitrene. The stabilization of active intermediate products depends on the chemical properties of the substituents and the conditions under which the process is carried out, and leads to a wide spectrum of final products for the thermal decomposition of tetrazoles. Kinetic studies of the thermolysis of tetrazoles show that the mechanism of heterocycle fragmentation can vary with varying temperature. The elimination of nitrogen from tetrazoles is preceded by a high-polarity transition state.
Top-30
Citations by journals
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1
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2 publications, 3.45%
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1 publication, 1.72%
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Journal of Molecular Structure THEOCHEM
1 publication, 1.72%
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Polymers
1 publication, 1.72%
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Journal of Inclusion Phenomena and Macrocyclic Chemistry
1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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Journal of Saudi Chemical Society
1 publication, 1.72%
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1 publication, 1.72%
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Small
1 publication, 1.72%
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Macromolecular Rapid Communications
1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 1.72%
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European Journal of Organic Chemistry
1 publication, 1.72%
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1
2
3
4
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Citations by publishers
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2
4
6
8
10
12
14
16
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Elsevier
16 publications, 27.59%
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Wiley
16 publications, 27.59%
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American Chemical Society (ACS)
7 publications, 12.07%
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Royal Society of Chemistry (RSC)
6 publications, 10.34%
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Springer Nature
5 publications, 8.62%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 3.45%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 1.72%
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King Saud University
1 publication, 1.72%
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Pleiades Publishing
1 publication, 1.72%
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Taylor & Francis
1 publication, 1.72%
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Belarusian State University
1 publication, 1.72%
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2
4
6
8
10
12
14
16
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lesnikovich A. et al. The thermal decomposition of tetrazoles // Thermochimica Acta. 1992. Vol. 200. pp. 427-441.
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Lesnikovich A., Levchik S., Balabanovich A., Ivashkevich O. A., Gaponik P. The thermal decomposition of tetrazoles // Thermochimica Acta. 1992. Vol. 200. pp. 427-441.
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TY - JOUR
DO - 10.1016/0040-6031(92)85135-i
UR - https://doi.org/10.1016/0040-6031(92)85135-i
TI - The thermal decomposition of tetrazoles
T2 - Thermochimica Acta
AU - Lesnikovich, A.I.
AU - Levchik, S.V.
AU - Balabanovich, A.I.
AU - Ivashkevich, Oleg A.
AU - Gaponik, P.N.
PY - 1992
DA - 1992/07/01 00:00:00
PB - Elsevier
SP - 427-441
VL - 200
SN - 0040-6031
SN - 1872-762X
ER -
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@article{1992_Lesnikovich,
author = {A.I. Lesnikovich and S.V. Levchik and A.I. Balabanovich and Oleg A. Ivashkevich and P.N. Gaponik},
title = {The thermal decomposition of tetrazoles},
journal = {Thermochimica Acta},
year = {1992},
volume = {200},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0040-6031(92)85135-i},
pages = {427--441},
doi = {10.1016/0040-6031(92)85135-i}
}